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Compound (A) C(8)H(9)Br. Gives a white p...

Compound (A) `C_(8)H_(9)Br`. Gives a white precipitate when warmed with alcoholic `AgNO_(3)`. Oxidation of (A) gives an acid (B). `C_(8)H_(6)O_(4)`. (B) easily forms anhydride on heating. Identify the compound (A)

A

B

C

D

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The correct Answer is:
D
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Compund (A)C_(8)H_(9) Br gives a white precipitate when warmed with alcoholic AgNO_(3) Oxidation of (A) gives an acid (B) C_(8) H_(6)O_(4) (B) easily anhydride on heating Identify the compound (A) .

Compound (A) and (B) are isomers having C_(8)H_(10) . On oxidation (A) gives benzoic acid while (B) gives phthalic acid which forms an anhydride (C) on heating. Identify (A), (B) and (C).

An organic compound (A) (C_(8)H_(14)O) forms an oxime and gives a positive haloform reaction. On ozonolysis, it gives acetone and a compound (B) (C_(5)H_(8)O_(2)) . (B) forms a dioxime and on subjecting to oxidation reaction gives an acid (C ) (C_(4)H_(6)O_(4)) . On treatment with excess of ammonia and strong heating, (C ) gives a neutral compound (D) (C_(4)H_(5)O_(2)N) . (D) on distillation with zinc dust forms pyrrloe. Suggest the possible structures of (A), (B), (C ), and (D). Explain the chemical reactions involved.

ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5
  1. In the reaction, the structure of the product T is:

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  2. Among the following compounds, the most acidic is:

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  3. Compound (A) C(8)H(9)Br. Gives a white precipitate when warmed with al...

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  4. In the reaction shown below the major product (s) formed is/are .

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  5. The reactivity of compound Z with different halogens under appropriat...

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  6. Consider the reaction sequence below:

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  7. Fluorination of an aromatic ring is easily accompolished by treating a...

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  8. The correct statement(s) about the following reaction sequence is (are...

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  9. Among the following reactions (s), which gives (give) tert-butyl benze...

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  10. For the reaction C(6)H(6)+(CH(3))(2)CHCH(2)Cl overset("Anhy".AlCl(3))r...

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  11. Complete the following reaction

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  12. The main product of the following reaction is C(6)H(5)CH(2)(OH)CH(CH(3...

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  13. Fill in the blanks with appropriate structure of reaction products in ...

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  14. Predict the structure of the intermediates/products in the following r...

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  15. Predict the product

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  16. The following reaction gives two products. Write the structures of the...

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  17. Predict the product

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  18. Predict the product

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  19. Covert

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  20. 7-bromo-1,3,5-cycloheptatriene exists as ionic species in aqueous solu...

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