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A compound [A] with molecular formula C(...

A compound [A] with molecular formula `C_(4)H_(10)O` reacts rapidly with metallic sodium but very slowly with Lucas reagent. When [A] treated with hot concentrated `H_(2)SO_(4)`, it gives a compound [B] `C_(4)H_(8)` which upon hydration with aqueous `H_(2)SO_(4)` forms a compound [C] with molecular formula `C_(4)H_(10)O`. The compound [C] is almost unert to metallic sodium but reacts rapidly with Lucas reagent. What are the compounds [A], [B] and [C] ? Explain the reaction involved.

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The correct Answer is:
`{:((CH_(3))_(2)CHCH_(2)OH;,(CH_(3))_(2)C=CH_(2);,(CH_(3))_(3)COH),(A,B,C):}`
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A compound (A) with molecular formula C_(4)H_(10)O reacts rapidly with metallic sodium but reacts very slowly with Lucas reagent. (A) when treated with hot concentrated H(2)SO_(4) gives a compound (B) , C_(4)H_(8) on hydration with aqueous H_(2)SO_(4) forms a compound (C ) with moolcular formula C_(4)H_(10)O . (C ) is almost inert to metallic sodium but reacts readily with Lucas reagent. What are (A),(B) and (C ) ? Explain the reactions involved.

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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-4[B]
  1. Explain why pyridine does not undergo Friedel-Craft's reaction?

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  2. A compound (A) reacts with thionylchloride to give a compound (B). (B)...

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  3. A compound [A] with molecular formula C(4)H(10)O reacts rapidly with m...

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  4. Give the product of the reaction of Ph(2)CHCH(2)OH with HBr and explai...

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  5. Hydration of 3-phenylbut-1-ene in dilute H(3)SO(4) forms 2-pheylbutan ...

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  6. When A given bel,ow reacts with HI products is B and not C. Explain

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  7. Isotopic carbon-14 in (A) appears at new position (As in B) (A) reacts...

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  8. Complete the following reaction CH(2)=CH(2)

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  9. Complete the following reactions (c ) CH(3)CH=CH(2)overset(m...

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  10. In the following dehydration of diol with H(3)PO(4) following product ...

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  11. In the following S(N)1 reaction: underset(S(N)1)overset(OH^(o+))rar...

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  12. Two different Grignard reagents (X) and (Y ) produce C(6)H(5)CH(2)C(CH...

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  13. A substance C(5)H(10)O does not reduce Fehling's solution, forms a phe...

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  14. A ketone A, which undergoes halform reaction, gives compound B on redu...

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  15. The sodium salt of a carboxylic acid (A) was produced by passing a gas...

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  16. A: CH(3)overset(O)overset(||)C Cl B: CH(3)overset(O)overset(||)CH (Ros...

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  17. When the compound shown was heated in refluxing hydrochloric acid, a c...

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  18. CH(3)COO^(-) (acetate ion) is more stable than C(2)H(5)O^(-) (ethoxide...

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  19. Which is more reactive in each pair towards S(N) reaction ? (A) CH(3...

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  20. overset(AlCl(2))rarrAunderset(HCl)overset(Zn(Hg))rarrBoverset(SOCl(2))...

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