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Acids have much higher boiling points th...

Acids have much higher boiling points than isomeric esters because :-

A

Acids form dimers by H-Bonding

B

Acids are volatile in steam

C

Ester are non-volatile

D

Acids can ionise to give protons in aqueous solution

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The correct Answer is:
A
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Knowledge Check

  • NH_(3) has higher boiling point than expected because

    A
    It froms `NH_(4)OH ` with water
    B
    It has intramolecular hydrogen bonds
    C
    It has intramolecular hydrogen bonds
    D
    Its density decreases bond on freezing
  • Polyhydroxy alcohols have higher boiling point than monohydric alcohols because :

    A
    The former have more than one OH group
    B
    The former have higher moleculare weights
    C
    The former shows higher hydrogen bonding
    D
    The latter are more volatile
  • Polyhydroxy alcohols have higher boiling point than monohydric alcohols because :

    A
    The former have more than one OH group
    B
    The former have higher moleculare weights
    C
    The former shows higher hydrogen bonding
    D
    The latter are more volatile
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    Assertion: Alkyl cyanides and alkyl isocyanides have much higher boiling points than corres- ponding alkyl halides. Reason : Cyanides and isocyanides are much more polar than alkyl halides.

    Alcohols have higher boiling points than parent hydrocarbons because of

    Ethanol has higher boiling point than ethanol because

    Tertiary amines have lowest boiling points amongst isomeric amines because:

    Assertion (A) : Alkyl cyanides as well as alkyl isocyanides have much higher boiling points than corresponding alkyl halides. Reason (R) : Cyanides and isocyanides are much more polar than alkyl halides.