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Give reasons for the following : 'Carb...

Give reasons for the following :
'Carbon-oxygen bond lengths in formic acid aer `1.23 Å` and `1.36 Å` and both carbon-oxygen bonds in sodium formate have the same value, i.e., `1.27 Å`.

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The correct Answer is:
Formate in shown equivalent resonating structures while formic acid coes not.
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The carbon-oxygen bond lengths in formic acid are equal.

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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-4[A]
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  2. Complete the following equations giving the structures of the major or...

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  3. Give reasons for the following : 'Carbon-oxygen bond lengths in form...

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  4. The second dissociation constant of fumaric acid is greater than malet...

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  5. Which is stronger conjugate base in each pair ? (A) overset(-)OH or ...

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  6. Which acid of each pair shown here would you expect to be stronger ? ...

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  7. What are A and B in the following ?

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  8. In the following reaction, trace the position of isotopic O^(18) CH(...

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  9. Write the reagents to carry out following conversions: CH(3)overset(...

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  10. overset(AlCl(3))rarrA, What is A ?

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  11. +NBStoXundersetunderset("(iii) "H(2)O^(+))("(ii) "CO(2),)overset("(i) ...

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  12. +Br(2)underset(.^(o+)OH)overset(0^(@)C)rarrA Write down the structur...

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  13. Arrange the following in decreasing basic order with proper reasoning.

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  14. Sulphanilic acid is not soluble in organic solvents. Explain ?

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  15. What is the order of basicity of the following compounds ? (i) CH(3)...

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  16. What is the order of basicity of the following compounds? (i) CH(3)N...

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  17. Unlike other aromatic amines, why is the following amine stongly basic...

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  18. In this compound which site acts as an acid and which as a base ?

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  19. Alkyl cyanides (CH(3)CN) when treated with hydrogen in presence of Pt ...

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  20. Write the compound (A) and (B) formed in this overset(NaNH(2))rarr(...

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