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The compound that will react most readil...

The compound that will react most readily with `NaOH` to from methanol is

A

`(CH_(3))_(4)N^(+)I^(-)`

B

`CH_(3)OCH_(3)`

C

`(CH_(3))_(3)S^(+)I^(-)`

D

`(CH_(3))_(3)CI`

Text Solution

Verified by Experts

It is understood from previous lessons that positive nitrogen is a stronger acid as compared to positive sulphur, and shall accept the electron pair more readily on an internal nucleophilic attack of the `OH^(+)` ion.
`(CH_(3))_(4)N^(+)I^(-)+NaOH rarr (CH_(3))_(4)N^(+)OH^(-)+NaI,(CH_(3))_(4)N^(+)OH^(-) overset(Delta)rarr (CH_(3))_(3)N+CH_(3)OH`
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