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In the following reaction sequence : R...

In the following reaction sequence :
`R-OH overset(P+I_(2))rarr R-I overset(AgNO_(2))rarr RNO_(2) overset(HNO_(2))rarr ` no reaction.
The alcohol is a :

A

primary alcohol

B

secondary alcohol

C

tertiary alcohol

D

phenol

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alcohol corresponds to the reaction sequence provided, we will analyze each step of the reaction and identify the type of alcohol involved. ### Step-by-Step Solution: 1. **Identify the Reaction Sequence**: The given reaction sequence is: \[ R-OH \overset{P + I_2}{\rightarrow} R-I \overset{AgNO_2}{\rightarrow} RNO_2 \overset{HNO_2}{\rightarrow} \text{no reaction} \] This sequence is indicative of the Victor-Mayer test, which is used to differentiate between primary, secondary, and tertiary alcohols. 2. **Understanding the Victor-Mayer Test**: - In the first step, the alcohol (R-OH) reacts with phosphorus and iodine to form an alkyl iodide (R-I). - In the second step, the alkyl iodide reacts with silver nitrate (AgNO2) to form a nitro compound (RNO2). - The final step involves treating the nitro compound with nitrous acid (HNO2), which typically leads to the formation of a diazonium salt or a stable compound. 3. **Analyzing the Types of Alcohol**: - **Primary Alcohol (1°)**: - Reacts in all steps and produces a colored product upon treatment with sodium hydroxide after the final step. - **Secondary Alcohol (2°)**: - Reacts similarly but produces a different color upon treatment with sodium hydroxide. - **Tertiary Alcohol (3°)**: - Does not react in the first step because it lacks an alpha hydrogen, thus no reaction occurs, leading to no further product formation. 4. **Conclusion**: - Since the final product shows "no reaction," we can conclude that the alcohol must be a tertiary alcohol (3°) because it does not undergo the initial reaction with phosphorus and iodine due to the absence of alpha hydrogen. ### Final Answer: The alcohol is a **tertiary alcohol**.

To determine which alcohol corresponds to the reaction sequence provided, we will analyze each step of the reaction and identify the type of alcohol involved. ### Step-by-Step Solution: 1. **Identify the Reaction Sequence**: The given reaction sequence is: \[ R-OH \overset{P + I_2}{\rightarrow} R-I \overset{AgNO_2}{\rightarrow} RNO_2 \overset{HNO_2}{\rightarrow} \text{no reaction} ...
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