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The compound which reacts fastest with L...

The compound which reacts fastest with Lucas reagent at room temperature is :

A

butan-1-ol

B

butan-2-ol

C

2-methylpropan-1-ol

D

2-methylpropan-2-ol

Text Solution

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The correct Answer is:
To determine which compound reacts fastest with Lucas reagent at room temperature, we need to understand the nature of the compounds involved and how they interact with the reagent. ### Step-by-Step Solution: 1. **Understand Lucas Reagent**: Lucas reagent is a mixture of hydrochloric acid (HCl) and zinc chloride (ZnCl2). It is used to differentiate between primary, secondary, and tertiary alcohols based on their reactivity. 2. **Identify Alcohol Types**: - **Primary Alcohols (1°)**: The hydroxyl (-OH) group is attached to a carbon that is connected to only one other carbon. They react slowly with Lucas reagent and often require heating to show turbidity. - **Secondary Alcohols (2°)**: The -OH group is attached to a carbon connected to two other carbons. They react moderately with Lucas reagent, showing turbidity in a few minutes at room temperature. - **Tertiary Alcohols (3°)**: The -OH group is attached to a carbon connected to three other carbons. They react very quickly with Lucas reagent, showing immediate turbidity at room temperature. 3. **Analyze Given Options**: - **Option 1: Butan-1-ol** (1° alcohol): This is a primary alcohol and will react slowly, requiring heat for turbidity. - **Option 2: Butan-2-ol** (2° alcohol): This is a secondary alcohol and will show turbidity in a few minutes at room temperature. - **Option 3: 2-Methylpropan-1-ol** (1° alcohol): This is also a primary alcohol and will react slowly, similar to butan-1-ol. - **Option 4: 2-Methylpropan-2-ol** (3° alcohol): This is a tertiary alcohol and will react immediately with Lucas reagent, showing turbidity right away. 4. **Conclusion**: Among the options, the tertiary alcohol (2-Methylpropan-2-ol) will react the fastest with Lucas reagent at room temperature, producing immediate turbidity. ### Final Answer: The compound which reacts fastest with Lucas reagent at room temperature is **2-Methylpropan-2-ol** (Option 4). ---

To determine which compound reacts fastest with Lucas reagent at room temperature, we need to understand the nature of the compounds involved and how they interact with the reagent. ### Step-by-Step Solution: 1. **Understand Lucas Reagent**: Lucas reagent is a mixture of hydrochloric acid (HCl) and zinc chloride (ZnCl2). It is used to differentiate between primary, secondary, and tertiary alcohols based on their reactivity. 2. **Identify Alcohol Types**: - **Primary Alcohols (1°)**: The hydroxyl (-OH) group is attached to a carbon that is connected to only one other carbon. They react slowly with Lucas reagent and often require heating to show turbidity. ...
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