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When glycol is heated with dicarboxylic ...

When glycol is heated with dicarboxylic acid, the products are:

A

Polyesters

B

Polyethers

C

Polyethylene

D

No reaction at all

Text Solution

AI Generated Solution

The correct Answer is:
To determine the products formed when glycol is heated with a dicarboxylic acid, we can follow these steps: ### Step 1: Identify the Reactants Glycol, specifically ethylene glycol, has the structure: \[ \text{HO-CH}_2-\text{CH}_2-\text{OH} \] This means it has two hydroxyl (-OH) groups. A dicarboxylic acid contains two carboxyl (-COOH) groups. For this example, we can consider terephthalic acid, which has the structure: \[ \text{HOOC-}C_6\text{H}_4-\text{COOH} \] ### Step 2: Understand the Reaction Type When glycol is heated with a dicarboxylic acid, a condensation reaction occurs. In this type of reaction, water is eliminated as the two reactants combine to form a larger molecule. ### Step 3: Mechanism of the Reaction During the heating process: - One -OH group from glycol and one -H from the carboxylic acid will be removed, resulting in the loss of water (H₂O). - This leads to the formation of an ester linkage (-COO-). ### Step 4: Formation of the Product The reaction results in the formation of a polymer known as a polyester. The general structure of the polyester formed from ethylene glycol and a dicarboxylic acid can be represented as: \[ \text{[-O-CH}_2-\text{CH}_2-\text{O-CO-]}_n \] where n indicates the number of repeating units in the polymer. ### Step 5: Conclusion The product formed when glycol is heated with a dicarboxylic acid is a polyester. ### Final Answer The products are polyesters. ---
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