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k(P) & k(C) are ….. for reaction at equ...

`k_(P) & k_(C)` are ….. for reaction at equilibrium of type `H_(2)(g) + Br_(2)(g) hArr 2HBr(g)`.

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To find the relationship between \( K_p \) and \( K_c \) for the reaction: \[ H_2(g) + Br_2(g) \rightleftharpoons 2HBr(g) \] we can follow these steps: ### Step 1: Understand the Definitions - \( K_p \) is the equilibrium constant in terms of partial pressures of the gases. - \( K_c \) is the equilibrium constant in terms of concentrations of the gases. ### Step 2: Use the Relationship Between \( K_p \) and \( K_c \) The relationship between \( K_p \) and \( K_c \) is given by the formula: \[ K_p = K_c \cdot R^{\Delta n} \cdot T^{\Delta n} \] where: - \( R \) is the universal gas constant. - \( T \) is the temperature in Kelvin. - \( \Delta n \) is the change in the number of moles of gas, calculated as the number of moles of products minus the number of moles of reactants. ### Step 3: Calculate \( \Delta n \) For the given reaction: - Products: \( 2 \) moles of \( HBr \) - Reactants: \( 1 \) mole of \( H_2 \) + \( 1 \) mole of \( Br_2 \) = \( 2 \) moles Now, calculate \( \Delta n \): \[ \Delta n = \text{(moles of products)} - \text{(moles of reactants)} = 2 - 2 = 0 \] ### Step 4: Substitute \( \Delta n \) into the Equation Since \( \Delta n = 0 \), we can substitute this into the relationship: \[ K_p = K_c \cdot R^{0} \] Since \( R^{0} = 1 \): \[ K_p = K_c \cdot 1 \] Thus, we have: \[ K_p = K_c \] ### Conclusion For the reaction \( H_2(g) + Br_2(g) \rightleftharpoons 2HBr(g) \), the relationship between \( K_p \) and \( K_c \) is: \[ K_p = K_c \]
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