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Van't Hoff factor for a dilute solution ...

Van't Hoff factor for a dilute solution of a `K_(2) [HgI4]` is :

A

2

B

1

C

3

D

zero

Text Solution

AI Generated Solution

The correct Answer is:
To find the Van't Hoff factor (i) for the dilute solution of \( K_2[HgI_4] \), we need to analyze how the compound dissociates in solution. ### Step-by-Step Solution: 1. **Identify the Compound**: The compound given is \( K_2[HgI_4] \). This indicates that it contains potassium ions (K\(^+\)) and the complex ion \([HgI_4]^{2-}\). 2. **Dissociation of the Compound**: When \( K_2[HgI_4] \) dissolves in water, it dissociates into its constituent ions. The dissociation can be represented as follows: \[ K_2[HgI_4] \rightarrow 2K^+ + [HgI_4]^{2-} \] 3. **Count the Number of Ions Produced**: From the dissociation equation: - 2 moles of \( K^+ \) ions are produced. - 1 mole of \([HgI_4]^{2-}\) ion is produced. Therefore, the total number of ions produced when 1 mole of \( K_2[HgI_4] \) dissolves is: \[ 2 \text{ (from K}^+\text{)} + 1 \text{ (from [HgI}_4]^{2-}\text{)} = 3 \text{ ions} \] 4. **Calculate the Van't Hoff Factor (i)**: The Van't Hoff factor (i) is defined as the total number of particles (ions) in solution after dissociation. Thus, for \( K_2[HgI_4] \): \[ i = 3 \] ### Final Answer: The Van't Hoff factor for a dilute solution of \( K_2[HgI_4] \) is **3**. ---
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