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A molecule of a substance has a perman...

A molecule of a substance has a permanent electric dipole moment of magnitude `10^(-29) `C m. A mole of this substance is polarized at low temperature by appling a strong elecrostatic field of magnitude `10^(6) V m^(-1)`. The direction of the field is suddenly changed by an angle of `60^(@)`. Estimate the heat released by the substance in aligning its dipole along the new direction of the field. For simplicity, assume `100%` polarisation of sample.

Text Solution

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Here, dipole moment of each molecule ` = 10 ^(-29)` C . As 1 mole of the substance contains `6 x 10^(23)` moelcules, total diople momemt of all the molecules .
` P = 6 xx 10^(23) xx 10^(-29) Cm = 6 xx 10^(-6) Cm`
Initial potenital energy ,
`U_(i) = - pEcos theta = - 6 xx 10^(-6) xx 10^(-6) cos 60^(@) = - 3J`
Final potential energy (when `theta = 60^(@)`)
`U_(f) = 6 xx 10^(-6) xx 10^(6) cos 60^(@) = - 3J`
Change in potential energy = - 3J - (-6J) = 3J
So ,there is loss is potential energy . This must be the energy released by the substance in the form of heat in aligning its dipoles .
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