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Find the radius of Li^(++) ions in its g...

Find the radius of `Li^(++)` ions in its ground state assuming Bohr's model to be valid.

A

`12xx10^(-10)m`

B

`12xx10^(-12)m`

C

`16xx10^(-10)m`

D

`18xx10^(-12)m`.

Text Solution

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The correct Answer is:
To find the radius of the `Li^(++)` ion in its ground state using Bohr's model, we can follow these steps: ### Step 1: Understand the Bohr's Model Formula According to Bohr's model, the radius of the nth orbit of an electron in a hydrogen-like atom is given by the formula: \[ r_n = \frac{0.529 \, n^2}{Z} \, \text{Å} \] where: - \( r_n \) is the radius of the nth orbit, - \( n \) is the principal quantum number (1 for ground state), - \( Z \) is the atomic number of the element. ### Step 2: Identify the Parameters for `Li^(++)` For the lithium ion `Li^(++)`: - The atomic number \( Z \) of lithium (Li) is 3. - Since we are looking for the ground state, the principal quantum number \( n \) is 1. ### Step 3: Substitute the Values into the Formula Now, we substitute \( n = 1 \) and \( Z = 3 \) into the formula: \[ r_1 = \frac{0.529 \times 1^2}{3} \, \text{Å} \] \[ r_1 = \frac{0.529}{3} \, \text{Å} \] ### Step 4: Calculate the Radius Calculating the above expression: \[ r_1 = 0.1763 \, \text{Å} \] To convert angstroms to meters, we use the conversion \( 1 \, \text{Å} = 10^{-10} \, \text{m} \): \[ r_1 = 0.1763 \times 10^{-10} \, \text{m} = 1.763 \times 10^{-11} \, \text{m} \] ### Step 5: Final Result Thus, the radius of the `Li^(++)` ion in its ground state is approximately: \[ r \approx 1.76 \times 10^{-11} \, \text{m} \]
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