Home
Class 12
CHEMISTRY
Calculate the enthalpy of vaporisation p...

Calculate the enthalpy of vaporisation per mole for ethanol. Given `DeltaS = 109.8 J K^(-1) mol^(-1)` and boiling point of ethanol is `78.5^(@)`.

Text Solution

Verified by Experts

We know that,
`DeltaS_("vapour")=(DeltaH_("Vapour"))/(T_(bp))`
Given, `DeltaS_("vapour")=109.8JK^(-1)mol^(-1)`
`T_(bp)=78.5+273=351.5K`
Substituting these values in above equation, we get
`109.8=(DeltaH_("vapour"))/(351.5)`
`DeltaH_("vapour")=38594.7J" "mol^(-1)`
`=38.594kJ" "mol^(-1)`.
Promotional Banner

Topper's Solved these Questions

  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Illustrations of Objective Questions|58 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Miscellaneous Numerical Examples|22 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise LINKED COMPRESHENSION TYPE QUESTIONS ( SECTION-VI)|4 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    OP TANDON|Exercise INTEGER|2 Videos

Similar Questions

Explore conceptually related problems

Ethanol boils at 78.4^@C and the enthalpy of vaporisation of ethanol is 42.4kJ mol^(-1) . Calculate the entropy of vaporisation of ethanol.

It the enthalpy of vaporization of benzene is 308/ kJ mol^(-1) at boiling point (80^(@)C) , calculate the entroy (j mol^(-1) K^(-1)) in changing it from liquid to vapor.

The value for DeltaH_(vap) and Delat S_(vap) for ethanol are respectively 38.594 kJ mol^(-1) and 109.8 JK^(-1) . The boiling point of ethanol will be

The enthalpy of vaporisation of a liquid is 30 kJ mol^(-1) and entropy of vaporisation is 75 J mol^(-1) K^(-1) . The boiling point of the liquid at 1atm is :

OP TANDON-Chemical Thermodynamics and Thermochemistry-Solved Example
  1. The enthalpy change for transition of liquid water to steam is 40.8 kJ...

    Text Solution

    |

  2. What is entropy change for the conversion of one gram of ice to water ...

    Text Solution

    |

  3. Calculate the enthalpy of vaporisation per mole for ethanol. Given Del...

    Text Solution

    |

  4. Calculate the entrpoy change for the following reversible process: a...

    Text Solution

    |

  5. What is the entropy change (in JK^(-1)mol^(-1)) when one mole of ice i...

    Text Solution

    |

  6. The enthalpy of vaporisation of liquid diethly ether -(C2H5)2O, is 26....

    Text Solution

    |

  7. Calculate entropy change when 10 moles of n ideal gas expands reversib...

    Text Solution

    |

  8. Oxygen gas weighing 64 g is expanded from 1 atm to 0.25 atm at 30^(@)C...

    Text Solution

    |

  9. Calculate the change in entropy when 1 mole nitrogen gas expands isoth...

    Text Solution

    |

  10. DeltaH and DeltaS for the reaction: Ag(2)O(s) rarr 2Ag(s) +(1//2)O(2...

    Text Solution

    |

  11. For the reaction 2NO(g)+O(2)(g)to2NO(2)g Calculate DeltaG at 700K ...

    Text Solution

    |

  12. In the reaction A^(+)+BtoA+B^(+) there is no entropy change. If enthal...

    Text Solution

    |

  13. DeltaH and DeltaS for the reaction Br(2)(l)+Cl(2)(g)to2BrCl(g) are 29....

    Text Solution

    |

  14. Calculate the temperature at which liquid water will be in equilibrium...

    Text Solution

    |

  15. Zinc reacts with dilute hydrochloric acid to give hydrogen at 17^(@)C....

    Text Solution

    |

  16. DeltaH and DeltaS for the system H(2)O(l) hArr H(2)O(g) at 1atm are 40...

    Text Solution

    |

  17. For the reaction, SOCI(2) +H(2)O rarr SO(2)+2HCI the enthalpy of r...

    Text Solution

    |

  18. The standard enthalpy and entropy changes for the reaction in equilibr...

    Text Solution

    |

  19. The standard Gibbs free energies for the reaction at 1773K are given b...

    Text Solution

    |

  20. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |