Home
Class 12
CHEMISTRY
The enthalpy of vaporisation of liquid d...

The enthalpy of vaporisation of liquid diethly ether `-(C_2H_5)_2O,` is `26.0kJmol(-1)` at its boiling point `(35.0^@C)`. Calculate `DeltaS` for conversion of : (a) liquid to vapour, and (b) vapour to liquid at `35^@C`.

Text Solution

Verified by Experts

(a). `DeltaS_("vaporisation")=(DeltaH_("vaporisation"))/(T_(bp))=(26000)/(308)`
`=84.42JK^(-1)mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Illustrations of Objective Questions|58 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Miscellaneous Numerical Examples|22 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise LINKED COMPRESHENSION TYPE QUESTIONS ( SECTION-VI)|4 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    OP TANDON|Exercise INTEGER|2 Videos

Similar Questions

Explore conceptually related problems

The enthalpy of vapourisation of liquid diethyl ether (C_(2)H_(5))_(2)O is 26.0 kJ mol^(-1) at its boiling point ( 25.0^(@)C ). Calculate DeltaS^(@) for the conversion of (a) liquid to vapour and (b) vapour to liquid at 35^(@)C .

The enthalpy of vaporisation of benzene (C_(6)H_(6)) is 30.8 kJ mol^(-1) at its boiling point (80.1^(@)C) . Calculate the entropy change in going from: a. liquid to vapour and b. vapour to liquid at 80.1^(@)C .

Enthalpy of vapourization of benzene is +35.3 kJ mol^(-1) at its boiling point of 80^(@)C . The entropy change in the transition of the vapour to liquid at its boiling points [in K^(-1) mol^(-1) ] is

The conversion of a liquid into its vapour at its boiling point is called ........

The enthalpy of vaporization of a certain liquid at its boiling point of 35^(@)C is 24.64 kJ "mol"^(-1) .The value of change in entropy for the process is

If the entropy of vaporisation of a liquid is 110 JK^(-1)mol^(-1) and its enthalpy of vaporisation is 50 kJ mol^(-1) . The boiling point of the liquid is

OP TANDON-Chemical Thermodynamics and Thermochemistry-Solved Example
  1. Calculate the entrpoy change for the following reversible process: a...

    Text Solution

    |

  2. What is the entropy change (in JK^(-1)mol^(-1)) when one mole of ice i...

    Text Solution

    |

  3. The enthalpy of vaporisation of liquid diethly ether -(C2H5)2O, is 26....

    Text Solution

    |

  4. Calculate entropy change when 10 moles of n ideal gas expands reversib...

    Text Solution

    |

  5. Oxygen gas weighing 64 g is expanded from 1 atm to 0.25 atm at 30^(@)C...

    Text Solution

    |

  6. Calculate the change in entropy when 1 mole nitrogen gas expands isoth...

    Text Solution

    |

  7. DeltaH and DeltaS for the reaction: Ag(2)O(s) rarr 2Ag(s) +(1//2)O(2...

    Text Solution

    |

  8. For the reaction 2NO(g)+O(2)(g)to2NO(2)g Calculate DeltaG at 700K ...

    Text Solution

    |

  9. In the reaction A^(+)+BtoA+B^(+) there is no entropy change. If enthal...

    Text Solution

    |

  10. DeltaH and DeltaS for the reaction Br(2)(l)+Cl(2)(g)to2BrCl(g) are 29....

    Text Solution

    |

  11. Calculate the temperature at which liquid water will be in equilibrium...

    Text Solution

    |

  12. Zinc reacts with dilute hydrochloric acid to give hydrogen at 17^(@)C....

    Text Solution

    |

  13. DeltaH and DeltaS for the system H(2)O(l) hArr H(2)O(g) at 1atm are 40...

    Text Solution

    |

  14. For the reaction, SOCI(2) +H(2)O rarr SO(2)+2HCI the enthalpy of r...

    Text Solution

    |

  15. The standard enthalpy and entropy changes for the reaction in equilibr...

    Text Solution

    |

  16. The standard Gibbs free energies for the reaction at 1773K are given b...

    Text Solution

    |

  17. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  18. What is the equilibrium constant K(c) for the following reaction at 40...

    Text Solution

    |

  19. For the equilibrium, PCI(5)(g) hArr PCI(3)(g) +CI(2)(g) at 25^(@)C K...

    Text Solution

    |

  20. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |