Home
Class 12
CHEMISTRY
For the reaction 2NO(g)+O(2)(g)to2NO(2...

For the reaction
`2NO(g)+O_(2)(g)to2NO_(2)g`
Calculate `DeltaG` at 700K when enthalpy and entropy changes are `-113.0kJ" "mol^(-1) and `-145J" "K^(-1)mol^(-1)` respectively.

Text Solution

Verified by Experts

We know that `DeltaG=DeltaH-TDeltaS`
Given, `DeltaH=-113kJ" "mol^(-1)`
`=-113000J" "mol^(-1)`
`DeltaS=-145J" "K^(-1)" "mol^(-1)`
`T=700K`
Substituting these values in the above equation,
we get
`DeltaG=-113000-700xx(-145)`
`=-11500J" "mol^(-1)`
`=-11.5kJ" "mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Illustrations of Objective Questions|58 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Miscellaneous Numerical Examples|22 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise LINKED COMPRESHENSION TYPE QUESTIONS ( SECTION-VI)|4 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    OP TANDON|Exercise INTEGER|2 Videos

Similar Questions

Explore conceptually related problems

For the reaction, 2NO_(g) + O_(2)(g) rarr 2NO_(2)(g) Calculate DeltaG at 700K when enthalpy and entropy changes are -113.0 kJ mol^(-1) and -145 J K^(-1) mol^(-1) , respectively.

Calculate the value of DeltaG at 700K for the reaction, nX to mB . Given that value of DeltaH=-113kJ mol^(-1) and DeltaS=-145JK^(-1)mol^(-1).

Show that the reaction CO(g) +(1//2)O_(2)(g) rarr CO_(2)(g) at 300K is spontaneous and exothermic, when the standard entropy change is -0.094 k J mol^(-1) K^(-1) . The standard Gibbs free energies of formation for CO_(2) and CO are -394.4 and -137.2kJ mol^(-1) , respectively.

For the reaction, Ag_(2)O(s)hArr2Ag(s)+(1)/(2)O_(2)(g) DeltaH,DeltaS and T are 40.63 kJ mol^(-1) , 108.8 JK^(-1)mol^(-1) and 373.4K respectively. Free energy change DeltaG of the reaction will be:

Calculate DeltaH for the reaction H_(2)(g)+1//2O_(2)(g)toH_(2)O(g) given the bond energies of H-H and O=O bonds and O-H bond are 433 kJ mol^(-1) , 492 kJ mol^(-1) and 464kJ" "mol^(-1) .

OP TANDON-Chemical Thermodynamics and Thermochemistry-Solved Example
  1. Oxygen gas weighing 64 g is expanded from 1 atm to 0.25 atm at 30^(@)C...

    Text Solution

    |

  2. Calculate the change in entropy when 1 mole nitrogen gas expands isoth...

    Text Solution

    |

  3. DeltaH and DeltaS for the reaction: Ag(2)O(s) rarr 2Ag(s) +(1//2)O(2...

    Text Solution

    |

  4. For the reaction 2NO(g)+O(2)(g)to2NO(2)g Calculate DeltaG at 700K ...

    Text Solution

    |

  5. In the reaction A^(+)+BtoA+B^(+) there is no entropy change. If enthal...

    Text Solution

    |

  6. DeltaH and DeltaS for the reaction Br(2)(l)+Cl(2)(g)to2BrCl(g) are 29....

    Text Solution

    |

  7. Calculate the temperature at which liquid water will be in equilibrium...

    Text Solution

    |

  8. Zinc reacts with dilute hydrochloric acid to give hydrogen at 17^(@)C....

    Text Solution

    |

  9. DeltaH and DeltaS for the system H(2)O(l) hArr H(2)O(g) at 1atm are 40...

    Text Solution

    |

  10. For the reaction, SOCI(2) +H(2)O rarr SO(2)+2HCI the enthalpy of r...

    Text Solution

    |

  11. The standard enthalpy and entropy changes for the reaction in equilibr...

    Text Solution

    |

  12. The standard Gibbs free energies for the reaction at 1773K are given b...

    Text Solution

    |

  13. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  14. What is the equilibrium constant K(c) for the following reaction at 40...

    Text Solution

    |

  15. For the equilibrium, PCI(5)(g) hArr PCI(3)(g) +CI(2)(g) at 25^(@)C K...

    Text Solution

    |

  16. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  17. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  18. For the water gas reaction, C(s) +H(2)O(g) hArr CO(g)+H(2)(g) the ...

    Text Solution

    |

  19. Calculate DeltaG^(Theta) for the conversion of oxygen to ozone, ((3)/(...

    Text Solution

    |

  20. Acetic acid CH(3)COOH can form a dimer (CH(3)COOH)(2) in the gas phase...

    Text Solution

    |