Home
Class 12
CHEMISTRY
For the water gas reaction, C(s) +H(2)...

For the water gas reaction,
`C(s) +H_(2)O(g) hArr CO(g)+H_(2)(g)`
the standard Gibbs free energy of reaction (at `1000K)` is `-8.1 kJ mol^(-1)`. Calculate its equilibrium constant.

Text Solution

Verified by Experts

We know that
`K="antilog"((-DeltaG^(@))/(2.303RT))` . . . .(i)
Given that, `DeltaG^(@)=-8.1kJ//mol`
`R=8.314xx10^(-3)kJ" "K^(-1)mol^(-1)`
Substituting these values in eq. (i), we get
`K="antilog"[(-(-8.1))/(2.303xx8.314xx10^(-3)xx1000)]`
`K=2.65`
Promotional Banner

Topper's Solved these Questions

  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Illustrations of Objective Questions|58 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Miscellaneous Numerical Examples|22 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise LINKED COMPRESHENSION TYPE QUESTIONS ( SECTION-VI)|4 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    OP TANDON|Exercise INTEGER|2 Videos

Similar Questions

Explore conceptually related problems

For the water gas reaction, C(s) +H_(2)O(g) hArr CO(g)+H_(2)(g) the standard Gobbs free energy of reaction (at 1000K) is -8.1 kJ mol^(-1) . Calculate its equilibrium constant.

For the water gas reaction: C(s) +H_(2)O(g) hArr CO(g) +H_(2)(g) the standard Gibbs enegry for the reaction at 1000K is -8.1 kJ mol^(-1) . Calculate its equilibriu constant.

For the water gas reaction C(s)+H_(2)O(g)hArrCO(g)+H_(2)(g) The standard Gibb's energy of energy of reaction (at 1000K) is -8.1KJmol^(-1) . Value of equilibrium constant is -

For the water gas reaction C(s) + H_(2)O(g) hArr CO(g) + H_(2)(g) At 1000K , the standard Gibbs free energy change of the reaction is -8.314KJ//mol . Therefore, at 1000K the equilibrium constant of the above water gas reaction is

The standard Gibbs energy change for the reaction 2SO_2(g) +O_2(g) to 2SO_3 (g) is -142 kJ mol^(-1) at 300 K. Calculate equilibrium constant.

Write the equilibrium constant of the reaction C(s)+H_(2)O(g)hArrCO(g)+H_(2)(g)

For the reaction H_(2)(g) + I_(2) (g) hArr 2HI (g), the standard free energy is DeltaG^(Theta) gt 0. the equilibrium constant (k) would be.

Equilibrium constant for the reaction: H_(2)(g) +I_(2) (g) hArr 2HI(g) is K_(c) = 50 at 25^(@)C The standard Gibbs free enegry change for the reaction will be:

Greenhouse gas CO_(2) can be converted to CO(g) by the following reaction CO_(2)(g)+H_(2)(g) rarr CO_(2)+H_(2)O(g) , termed as water gas reaction. Calculate equilibrium constants K_(p) for the water gas reaction at 1000K .H=35040J/mol & S=32.11J/ mol/k

OP TANDON-Chemical Thermodynamics and Thermochemistry-Solved Example
  1. Oxygen gas weighing 64 g is expanded from 1 atm to 0.25 atm at 30^(@)C...

    Text Solution

    |

  2. Calculate the change in entropy when 1 mole nitrogen gas expands isoth...

    Text Solution

    |

  3. DeltaH and DeltaS for the reaction: Ag(2)O(s) rarr 2Ag(s) +(1//2)O(2...

    Text Solution

    |

  4. For the reaction 2NO(g)+O(2)(g)to2NO(2)g Calculate DeltaG at 700K ...

    Text Solution

    |

  5. In the reaction A^(+)+BtoA+B^(+) there is no entropy change. If enthal...

    Text Solution

    |

  6. DeltaH and DeltaS for the reaction Br(2)(l)+Cl(2)(g)to2BrCl(g) are 29....

    Text Solution

    |

  7. Calculate the temperature at which liquid water will be in equilibrium...

    Text Solution

    |

  8. Zinc reacts with dilute hydrochloric acid to give hydrogen at 17^(@)C....

    Text Solution

    |

  9. DeltaH and DeltaS for the system H(2)O(l) hArr H(2)O(g) at 1atm are 40...

    Text Solution

    |

  10. For the reaction, SOCI(2) +H(2)O rarr SO(2)+2HCI the enthalpy of r...

    Text Solution

    |

  11. The standard enthalpy and entropy changes for the reaction in equilibr...

    Text Solution

    |

  12. The standard Gibbs free energies for the reaction at 1773K are given b...

    Text Solution

    |

  13. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  14. What is the equilibrium constant K(c) for the following reaction at 40...

    Text Solution

    |

  15. For the equilibrium, PCI(5)(g) hArr PCI(3)(g) +CI(2)(g) at 25^(@)C K...

    Text Solution

    |

  16. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  17. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  18. For the water gas reaction, C(s) +H(2)O(g) hArr CO(g)+H(2)(g) the ...

    Text Solution

    |

  19. Calculate DeltaG^(Theta) for the conversion of oxygen to ozone, ((3)/(...

    Text Solution

    |

  20. Acetic acid CH(3)COOH can form a dimer (CH(3)COOH)(2) in the gas phase...

    Text Solution

    |