Calculate `DeltaH_(f)^(@)` for chloride ion from the following data `:`
`(1)/(2)H_(2(g))+(1)/(2)Cl_(2(g))rarr HCl_((g)),DeltaH_(f)^(@)=-92.4kJ`
`HCl_((g))+nH_(2)O rarr H_((aq.))^(+)+Cl_((aq.))^(-),DeltaH^(@)=-74.8kJ`
`DeltaH_(f)^(@) H_((aq.))^(+)=0.0kJ`

Calculate Delta H^(@)._(f) for chloride ion from the following data : (1)/(2)H_(2)(g) + (1)/(2)Cl_(2)(g) rarr HCI(g), Delta H^(@)._(f) = -92.4 kJ HCI(g) + nH_(2)O rarr H^(+) (aq) + CI^(-)(aq), Delta H^(@) = - 74.8 kJ Delta H^(@)._(f) H^(+) (aq) = 0.0 kJ

Calculate the standard enthalpy of formation of acetylene from the following data : C_((g))+O_(2(g))rarr CO_(2(g)),DeltaH^(@)=-393kJ mol^(-1) H_(2(g))+(1)/(2)O_(2(g)) rarr H_(2)O_((l)),DeltaH^(@)=-285.8kJ mol^(-1) 2C_(2)H_(2(g))+5O_(2(g))rarr 4CO_(2(g))+2H_(2)O_((l)),DeltaH^(@)=-2598.8kJ mol^(-1) .

Calculate the enthalpy of formation of anhydrous aluminium chloride, Al_(2)Cl_(6) from the following data : (i) 2Al(s) + 6HCl (aq) to Al_(2)Cl_(6) (aq) + 3H_(2)(g), Delta_(r)H^(@) = -1004.0 kJ (ii) H_(2)(g) + Cl_(2)(aq) to 2HCl(g) , Delta_(r)H^(@) = -183.9 kJ , Delta_(r)H^(@) = -183.9 kJ (iii) HCl(g) + aq to HCl(aq), Delta_(r)H^(@) = -73.2 kJ Al_(2)Cl_(6)(s) + aq to Al_(2) Cl_(2)(aq) , Delta_(r)H^(@) = -643.0 kJ

Calculate the heat of combustion of benzene form the following data: a. 6C(s) +3H_(2)(g) rarr C_(6)H_(6)(l), DeltaH = 49.0 kJ b. H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l), DeltaH =- 285.8 kJ c. C(s) +O_(2) (g) rarr CO_(2)(g), DeltaH =- 389.3 kJ

Calculate the heat of formation of n butane from the followinf data: a. 2C_(4)H_(10)(g) +13O_(2)(g) rarr 8CO_(2)(g) +10H_(2)O(l), DeltaH = - 5757.2 kJ b. C(s) +O_(2) (g)rarrCO_(2)(g), DeltaH =- 405.4 kJ c. 2H_(2)(g) +O_(2)(g) rarr 2H_(2)O(l), DeltaH =- 572.4 kJ

Calculate the resonance enegry of toulene (use Kekule structure form the following data C_(7)H_(8)(l) +9O_(2)(g) rarr 7CO_(2)(g) +4H_(2)O(l)+ DeltaH, DeltaH^(Theta) =- 3910 kJ mol^(-1) C_(7)H_(8)(l) rarr C_(7)H_(8)(g), DeltaH^(Theta) = 38.1 kJ mol^(-1) Delta_(f)H^(Theta) (water) =- 285.8 kJ mol^(-1) Delta_(f)H^(Theta) [CO_(2)(g)] =- 393.5 kJ mol^(-1) Heat of atomisaiton of H_(2)(g) = 436.0 kJ mol^(-1) Heat of sulimation of C(g) = 715.0 kJ mol^(-1) Bond energies of C-H, C-C , and C=C are 413.0, 345.6 , and 610.0 kJ mol^(-1) .

Calculate the enthalpy of formation of Delta_(f)H for C_(2)H_(5)OH from tabulated data and its heat of combustion as represented by the following equaitons: i. H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(g), DeltaH^(Theta) =- 241.8 kJ mol^(-1) ii. C(s) +O_(2)(g) rarr CO_(2)(g),DeltaH^(Theta) =- 393.5kJ mol^(-1) iii. C_(2)H_(5)OH (l) +3O_(2)(g) rarr 3H_(2)O(g) + 2CO_(2)(g), DeltaH^(Theta) =- 1234.7kJ mol^(-1) a. -2747.1 kJ mol^(-1) b. -277.7 kJ mol^(-1) c. 277.7 kJ mol^(-1) d. 2747.1 kJ mol^(-1)