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DeltaH and DeltaS for the reaction: Ag...

`DeltaH` and `DeltaS` for the reaction:
`Ag_(2)O(s) rarr 2Ag(s) +(1//2)O_(2)(g)`
are `30.56 kJ mol^(-1)` and `66.0 J JK^(-1) mol^(-1)` respectively. Calculate the temperature at which free energy change for the reaction will be zero. Predict whether the forward reaction will be favoured above or below this temperature.

Text Solution

Verified by Experts

Calculate T by applying the formula
`DeltaG=DeltaH-TDeltaS and DeltaG=0`
Then find the vlaue of `DeltaG` at lower temperature than T. the value of `DeltaG` becomes positive, Hence, the reverse reaction will be favoured. AT temperature higher than T, the reaction is spontaneous.
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Delta H and Delta S for the reaction, Ag_(2)O(s)to 2A(s)+(1)/(2)O_(2)(g) , are 30.56 kJ mol^(-1) and 66.0 J mol^(-1) respectively. Calculate the temperature at which this reaction will be at equilibrium. Predict whether the forward reaction will be favoured above or below this temperature.

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