Home
Class 12
CHEMISTRY
A piston filled with 0.04 mole of an ide...

A piston filled with `0.04` mole of an ideal gas expands reversible from `50.0mL` at a constant temperature of `37.0^(@)C` . As it does so, it absorbs `208J` of heat. The value of `q` and `W` for the process will be `(R=8.314J//molK` , `1n7.5=2.01)`

A

`q=-208J,w=+208J`

B

`q=+208J,w=+208J`

C

`q=+208J,w=-208J`

D

`q=-208J,w=-208J`

Text Solution

Verified by Experts

The correct Answer is:
C

heat is absorbed hence, q will be posititve
I.e., `q=+208J`
`w=2.303nRT" log "((V_(2))/(V_(1)))`
`=2.303xx0.04xx8.314xx310" log "((375)/(50))`
`=208J`
`w_(("expansion"))=-208J`
work of expansion will be negative since, it is work done by the system.
Promotional Banner

Topper's Solved these Questions

  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Set 2|18 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Objective Question Level B|56 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Practice problems|81 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise LINKED COMPRESHENSION TYPE QUESTIONS ( SECTION-VI)|4 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    OP TANDON|Exercise INTEGER|2 Videos

Similar Questions

Explore conceptually related problems

A piston fielld with 0.04 mole of an ideal gas expands eversible from 50.0mL at a constant temperature of 37.0^(@)C . As it does so, it absorbe 208J of heat. The value of q and W for the process will be (R=8.314J//molK , 1n7.5=2.01)

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0^(@)C . As it does so, it absorbs 208 J of heat. The value of q and w for the process will be: (R=8.314J//molK)(ln 7.5=2.01)

A piston filled with 0.04 mole of an ideal gas expands reversible from 50.0 mL to 375 mL at a constant temperature of 37.0^(@)C . As it does so, it absorbs 208 J of heat. The values of q and w for the process will be: (R=3.14J/molK) (in 7.5=2.01)

OP TANDON-Chemical Thermodynamics and Thermochemistry-Objective Question Level-A
  1. On the basis of the following thermochemical data : (Delta(f)G^(@)H((a...

    Text Solution

    |

  2. The Habar's process of production of ammonia involves the equilibrium:...

    Text Solution

    |

  3. In which reaction there will be increase in entropy ?

    Text Solution

    |

  4. The species which by definition has zero standard molar enthalpy of fo...

    Text Solution

    |

  5. The standard enthalpy of formation of NH(3) is -46.0KJ mol^(-1) . If t...

    Text Solution

    |

  6. A 1.0g sample of substance A at 100^(@)C is added to 100 mL of H(2)O ...

    Text Solution

    |

  7. The entropy change involved in the isothermal reversible expansion of ...

    Text Solution

    |

  8. The incorrect expression among the following is

    Text Solution

    |

  9. Using the data provided, calculate the multiple bond energy (kJ mol^(-...

    Text Solution

    |

  10. The approxiamte standard enthalpies of formation of methanol and octan...

    Text Solution

    |

  11. The sysmbols F,H,S,V(m) and E^(@) denote Helmholtz free energy, enthal...

    Text Solution

    |

  12. A piston filled with 0.04 mole of an ideal gas expands reversible from...

    Text Solution

    |

  13. For the complete combustion of ethanol, C(2)H(5)OH(l)+3O(2)(g)rarr2CO(...

    Text Solution

    |

  14. The standed free energy of fromation of NO(g) is 86.6 kj/ mol at 298...

    Text Solution

    |

  15. The enthalpies of combustion of carbon and carbon monoxide are -393.5 ...

    Text Solution

    |

  16. deltaU is equal to

    Text Solution

    |

  17. Given C(("graphite"))+O(2)(g)toCO(2)(g), Delta(r)H^(0)=-393.5kJ" "mo...

    Text Solution

    |

  18. Which of the following lines correctly show the temperatrue dependence...

    Text Solution

    |

  19. The combustion of benzene (l) gives CO(2)(g) and H(2)O(l). Given that ...

    Text Solution

    |

  20. If 1.5 L of an ideal gas at a apressure of 20 atm expands isothermally...

    Text Solution

    |