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Fe(2)O(2)(s)+(3)/(2)C(s)to(3)/(2)CO(2)(g...

`Fe_(2)O_(2)(s)+(3)/(2)C(s)to(3)/(2)CO_(2)(g)+2Fe(s)`
`DeltaH^(@)=+234.12KJ `
`C(s)+O_(2)(g)toCO_(2)(g) DeltaH^(@)=-393.5KJ`
Use these equations and `DeltaH^(@)` value to calculate `DeltaH^(@)` for this reaction :
`4Fe(s)+3O_(2)(g)to2Fe_(2)O_(3)(s)`

A

`-1648.7kJ`

B

`-1255.3 kJ`

C

`-1021.2kJ`

D

`-129.4kJ`

Text Solution

Verified by Experts

The correct Answer is:
A

`2Fe(s)+(3)/(2)CO_(2)(g)toFe_(2)O_(3)(s)+(3)/(2)C(s)" "(DeltaH^(@)=-234.1kJ)` . . .(i)
`C(s)+O_(2)(g)toCO_(2)(g)" "(DeltaH^(@)=-393.5kJ)` . . . (ii)
Multiplying eq. (i) by 2 and eq. (ii) by 3 and on adding both equations, we get:
`4Fe(s)+3O_(2)(g)to2Fe_(2)O_(3)(s)," "DeltaH^(@)=(-234.1xx2)+(-3xx393.5)`
`=-1648.7kJ`
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OP TANDON-Chemical Thermodynamics and Thermochemistry-Objective Question Level B
  1. A large positive value of DeltaG^(ɵ) corresponds to which of these?

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  2. Consider the values of DeltaH("in" kJ mol^(-)) and for DeltaS("in" mol...

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  3. Fe(2)O(2)(s)+(3)/(2)C(s)to(3)/(2)CO(2)(g)+2Fe(s) DeltaH^(@)=+234.12K...

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  4. Consider this equation and the associated value for DeltaH^(@). 2H(2...

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  5. The internal energy (U) of an ideal gas decreases by the same amount a...

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  6. The enthalpy of neutralisation of a strong acid by a string base is -5...

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  7. For which process will DeltaH and DeltaG^(@) be expected to be most si...

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  8. For a particular reaction, DeltaH=-38.3 kJ and DeltaS^(@)=-113JxxK^(-1...

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  9. Which halogen in its standard state has the greatest absolute entropy ...

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  10. For which of these processes is the value of Delta S negative? i. Su...

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  11. When solid NH(4)NO(3) is dissolved in water at 25^(@)C, the temperatur...

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  12. The diagram below shows the heat of reaction between N(2),O(2) NO and ...

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  13. The enthalpy changes for two reactions are given by the equations: 2...

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  14. The enthalpy changes at 298 K in successive breaking of O-H bonds of ...

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  15. Consider the following two reactions: i. Propene +H(2) rarr Propane,...

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  16. Under which circumstances would the free energy change for a reaction ...

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  17. Using the Gibbs energy change, Delta G^(@)=+ 63.3 kJ, for the followin...

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  18. Which statement (s) is/are true? 1. S^(Theta) values for all element...

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  19. The enthalpy of reaction does not depend upon:

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  20. A solution of 200 mL of 1 M KOH is added to 200 mL of 1 M HCl and the ...

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