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Equivalent conductances of NaCl, HCl and...

Equivalent conductances of `NaCl, HCl` and `CH_(3)COONa` at infinite dilution are 126.45, 426.16 and 91 `ohm^(-1) cm^(2) eq^(-1)` respectively. The equivalent conductance of `CH_(3)COOH` at infinite dilution would be :

A

`101.38 ohm^(-1) cm^(2) eq^(-1)`

B

`253.62 ohm^(-1) cm^(2) eq^(-1)`

C

`390.71 ohm^(-1) cm^(2) eq^(-1)`

D

`678.90 ohm^(-1) cm^(2) eq^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

`Lambda_(CH_(3)COOH)^(@)=Lambda_(CH_(3)COONa)^(@)+Lambda_(HCl)^(@)-Lambda_(NaCl)^(@)`
`=91+426.16-126.45`
`=390.71 ohm^(-1) cm^(2) eq^(-1)`
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