Home
Class 12
CHEMISTRY
Using Nernst equation for the cell react...

Using Nernst equation for the cell reaction,
`Pb+Sn^(2+) rarr Pb^(2+)+Sn`
Calculate the ratio `([Pb^(2+)])/([Sn^(2+)])` for which `E_(cell)=0`
(Given : `E_(Pb//Pb^(2+))^(@)=0.13` volt and `E_(Sn^(2+)//Sn)^(@)=-0.14` volt)

Text Solution

Verified by Experts

The correct Answer is:
`([Pb^(2+)])/([Sn^(2+)])=0.5`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    OP TANDON|Exercise OBJECTIVE TYPE QUESTION (LEVEL -A)|194 Videos
  • ELECTROCHEMISTRY

    OP TANDON|Exercise OBJECTIVE TYPE QUESTION (LEVEL -B)|52 Videos
  • ELECTROCHEMISTRY

    OP TANDON|Exercise ILLUSTRATIONS|28 Videos
  • COORDINATION COMPOUNDS

    OP TANDON|Exercise SBJECTIVE TYPE|96 Videos
  • HALOALKANES AND HALOARENES

    OP TANDON|Exercise Single Interger answer type questions|14 Videos

Similar Questions

Explore conceptually related problems

Calculate the e.m.f. of the cell, Zn(s)//Zn^(2+)(0.1 M) || Pb^(2+)(0.02 M)//Pb(s) E_(Zn^(2+)//Zn)^(@)=-0.76" V " and E_(Pb^(2+)//Pb)^(@)=-0.13" V "

What is the cell potential of the following cell ? Zn(s)|Zn^(2+)(1.0M)||Pb^(2+)(1.0M)|Pb(s) Given : E_(Pb^(2+)//Pb)^(@)=-0.12" V and " E_(Zn^(2+)//Zn)^(@)=-0.76" V"

Calculate the value of equilibrium constant for the reaction taking place between Cu(II) and Sn (II) ions in aqueous solution at 298 K. Given : E_(cu^(2+)//cu)^(@)=0.34" V" , E_(Sn^(2+)//Sn^(4+))^(@)=-0.154" V" .

For an electrochemical cell Sn(s)Sn^(2+) (aq,1M)||pb^(2+) (Aq,1M)|Pb(s) the ratio ([Sn^(2+)])/([Pb^(2+)] when this cell attians equilibrium is_______ (Given : E_(sn^(2+)|Sn)^(@) = -0.14V, E_(pb^(2+|Pb^(@))= -0.13V, (2.303RT)/(F = 0.06))

OP TANDON-ELECTROCHEMISTRY-PRACTICE PROBLEMS
  1. The emf of the cell, Ag|AgI (0.05) MKI|| (0.05) M AgNO(3)|Ag is 0....

    Text Solution

    |

  2. At equimolar concentrations of Fe^(2+) and Fe^(3+), what must [Ag^(+)]...

    Text Solution

    |

  3. Using Nernst equation for the cell reaction, Pb+Sn^(2+) rarr Pb^(2+)...

    Text Solution

    |

  4. Determine the potential of a Daniell cell, initially containing 1.00 L...

    Text Solution

    |

  5. Calculate the standard potential for the reaction, Hg(2)Cl(2)+Cl(2) ...

    Text Solution

    |

  6. Given : {:(Cu^(2+)+e^(-) rarr Cu^(+),,E^(@)=0.15" volt"),(Cu^(+)+e^(...

    Text Solution

    |

  7. What is the standard electrode potential for the electrode MnO(4)^(-)/...

    Text Solution

    |

  8. What ratio of Pb^(2+) to Sn^(2+) concentration is needed to reverse th...

    Text Solution

    |

  9. For the cell Mg|Mg^(2+)||Ag^(+)|Ag, calculate the equilibrium constant...

    Text Solution

    |

  10. Determine the potential for the cell : Pt|Fe^(2), Fe^(3+)||Cr(2)O(7)...

    Text Solution

    |

  11. For the measurement of the solubility product of AgCl the following ce...

    Text Solution

    |

  12. Excess of AgCl is added to 0.1 M solution of KBr at 298 K. Calculate t...

    Text Solution

    |

  13. The emf of the cell Cu|underset(a=0.1)(CuSO(4))||underset(x)(CuSO(4))|...

    Text Solution

    |

  14. The cell, Pt|H(2)" (1 atm)"||H^(+) (pH=x)| normal calomel electrode,...

    Text Solution

    |

  15. The standard reduction potential for Cu^(2+)//Cu is +0.34 V. Calculate...

    Text Solution

    |

  16. The standard free enrgy change for the reaction, H(2)(g) +2AgCl(s) r...

    Text Solution

    |

  17. For the reaction, Fe^(3+)+3e^(-) hArr Fe, E^(@) is -0.036 volt and the...

    Text Solution

    |

  18. The standard reduction potential at 25^(@)C of the reaction 2H(2)O+2e^...

    Text Solution

    |

  19. calculate the emf of the following cell: Pt(H(2)" 1 atm")|CH(3)CH(2)...

    Text Solution

    |

  20. Calculate equilibrium constant for I(2)+I^(-) hArr I(3)^(-) at 298...

    Text Solution

    |