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Conductors allow the passage of electric...

Conductors allow the passage of electric current through them. Metallic and electrolytic are the two type of conductors. Current carriers in metallic and electrolytic conductors are free electrons and free ions respectively. Specific conductance or consuctivity of the electrolyte solution is given by the following relation :
`kappa=c xx l/A`
where, `c=1//R` is the conductance and `l//A` is the cell constant. Molar conductance `(Lambda_(m))` and equivalence conductance `(Lambda_(e))` of an electrolyte solution are calculated using the following similar relations :
`Lambda_(m)= kappa xx 1000/M`
`Lambda_(e)= kappa xx 1000/N`
Where, M and N are the molarity and normality of the solution respectively. Molar conductance of strong electrolyte depends on concentration :
`Lambda_(m)=Lambda_(m)^(@)-b sqrt(c)`
where, `Lambda_(m)^(@)=` molar conductance at infinite dilution
c= concentration of the solution
b= constant
The degrees of dissociation of weak electrolytes are calculated as :
`alpha=Lambda_(m)/Lambda_(m)^(@)=Lambda_(e)/Lambda_(e)^(@)`
Which of the following equality holds good for the strong electrolytes ?

A

`Lambda=Lambda^(@)` as `c rarr 1`

B

`Lambda=Lambda^(@)` as `c rarr 0`

C

`Lambda=Lambda^(@)` as `c rarr oo`

D

`Lambda=Lambda^(@)` as `c rarr sqrt(b)`

Text Solution

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The correct Answer is:
B
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Conductors allow the passage of electric current through them. Metallic and electrolytic are the two type of conductors. Current carriers in metallic and electrolytic conductors are free electrons and free ions respectively. Specific conductance or consuctivity of the electrolyte solution is given by the following relation : kappa=c xx l/A where, c=1//R is the conductance and l//A is the cell constant. Molar conductance (Lambda_(m)) and equivalence conductance (Lambda_(e)) of an electrolyte solution are calculated using the following similar relations : Lambda_(m)= kappa xx 1000/M Lambda_(e)= kappa xx 1000/N Where, M and N are the molarity and normality of the solution respectively. Molar conductance of strong electrolyte depends on concentration : Lambda_(m)=Lambda_(m)^(@)-b sqrt(c) where, Lambda_(m)^(@)= molar conductance at infinite dilution c= concentration of the solution b= constant The degrees of dissociation of weak electrolytes are calculated as : alpha=Lambda_(m)/Lambda_(m)^(@)=Lambda_(e)/Lambda_(e)^(@) Which of the following decreases on dilution of electrolyte solution ?

Conductors allow the passage of electric current through them. Metallic and electrolytic are the two type of conductors. Current carriers in metallic and electrolytic conductors are free electrons and free ions respectively. Specific conductance or consuctivity of the electrolyte solution is given by the following relation : kappa=c xx l/A where, c=1//R is the conductance and l//A is the cell constant. Molar conductance (Lambda_(m)) and equivalence conductance (Lambda_(e)) of an electrolyte solution are calculated using the following similar relations : Lambda_(m)= kappa xx 1000/M Lambda_(e)= kappa xx 1000/N Where, M and N are the molarity and normality of the solution respectively. Molar conductance of strong electrolyte depends on concentration : Lambda_(m)=Lambda_(m)^(@)-b sqrt(c) where, Lambda_(m)^(@)= molar conductance at infinite dilution c= concentration of the solution b= constant The degrees of dissociation of weak electrolytes are calculated as : alpha=Lambda_(m)/Lambda_(m)^(@)=Lambda_(e)/Lambda_(e)^(@) For which of the following electrolytic solution Lambda_(m) and Lambda_(e) are equal ?

Conductors allow the passage of electric current through them. Metallic and electrolytic are the two type of conductors. Current carriers in metallic and electrolytic conductors are free electrons and free ions respectively. Specific conductance or consuctivity of the electrolyte solution is given by the following relation : kappa=c xx l/A where, c=1//R is the conductance and l//A is the cell constant. Molar conductance (Lambda_(m)) and equivalence conductance (Lambda_(e)) of an electrolyte solution are calculated using the following similar relations : Lambda_(m)= kappa xx 1000/M Lambda_(e)= kappa xx 1000/N Where, M and N are the molarity and normality of the solution respectively. Molar conductance of strong electrolyte depends on concentration : Lambda_(m)=Lambda_(m)^(@)-b sqrt(c) where, Lambda_(m)^(@)= molar conductance at infinite dilution c= concentration of the solution b= constant The degrees of dissociation of weak electrolytes are calculated as : alpha=Lambda_(m)/Lambda_(m)^(@)=Lambda_(e)/Lambda_(e)^(@) The conductance of a solution of an electrolyte is equal to that of its specific conductance. The cell constant of the conductivity cell is equal to :

Conductors allow the passage of electric current through them. Metallic and electrolytic are the two type of conductors. Current carriers in metallic and electrolytic conductors are free electrons and free ions respectively. Specific conductance or consuctivity of the electrolyte solution is given by the following relation : kappa=c xx l/A where, c=1//R is the conductance and l//A is the cell constant. Molar conductance (Lambda_(m)) and equivalence conductance (Lambda_(e)) of an electrolyte solution are calculated using the following similar relations : Lambda_(m)= kappa xx 1000/M Lambda_(e)= kappa xx 1000/N Where, M and N are the molarity and normality of the solution respectively. Molar conductance of strong electrolyte depends on concentration : Lambda_(m)=Lambda_(m)^(@)-b sqrt(c) where, Lambda_(m)^(@)= molar conductance at infinite dilution c= concentration of the solution b= constant The degrees of dissociation of weak electrolytes are calculated as : alpha=Lambda_(m)/Lambda_(m)^(@)=Lambda_(e)/Lambda_(e)^(@) The correct order of equivalent conductances at infinite dilution of LiCl, NaCl and KCl is :

The molar conductivity of strong electrolyte

Conductivity of an electrolytic solution depends on:

The conductivity of Electrolytic solution depends on-

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