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For the reaction A + Brarr C +D, if conc...

For the reaction `A + Brarr C +D`, if concentratiton of A is doubled without altering the concentration of B, the rate gets doubling, If the concentration of B is increased by nine times without altering the concentration of A, the rate gas tripled. The order of reaction is

A

2

B

1

C

`3//2`

D

`4//3`

Text Solution

Verified by Experts

Rate = `k[A]^(alpha)[B](beta)" " (i)`
`2xx"rate" k[2A]^(alpha)[B](beta)" " (ii)`
`3xx"rate"= k[A]^(alpha)[9B](beta)" " (iii)`
From eqs. (i) and (ii), `alpha=1`
From eqs. (i) and (iii) ,`beta=1//2`
Order `=alpha+beta=1(1)/(2)=(3)/(2)`
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