Home
Class 12
CHEMISTRY
The reaction , 2N(2)O(5)rarr4NO(2)+O(2...

The reaction ,
`2N_(2)O_(5)rarr4NO_(2)+O_(2)`
was studdied and the following data were collected :

Determine (i) order the reaction (ii) the rate law and (iii) rate constant for the reaction

Text Solution

Verified by Experts

Let the rate law for the reaction be
Rate =`k[N_(2)O_(5)]^(x)`
`34xx10^(-5)=k[1.13xx10^(-2)]^(x)`
`25xx10^(-5)=k[0.84xx10^(-2)]^(x)`
`(25xx10^(-5))/(25xx10^(-5))=([1.13xx10^(-2)]^(2))/[0.84xx10^(-2)]^(x)`
`1.36=[1.345]^(x)`
Order of the reaction is 1. Rate law = `k[N_(2)O_(5)]`
`k=("Rate")/([N_(2)O_(5)])=(34.xx10^(-5))/(1.13xx10^(-2))=30.08xx10^(-3) "min"^(-1)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-A)|192 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-B) SET I|48 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise ILLUSTRATIONS|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    OP TANDON|Exercise Integer|4 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos

Similar Questions

Explore conceptually related problems

For the reaction 2N_(2)O_(5 )rarrNO_(2)+O_(2) rate of reaction is :

The rate law of the reaction 2N_2O_5 rarr4NO_2+O_2 is

For the reaction, 2NO+2H_(2)rarrN_(2)+2H_(2)O , the following kinetic data were obtained. Determine the rate law and the rate constant

For the reaction 2NO_(2)rarr2NO+O_(2) , rate expressed as :

For a reaction 2P + Q to S , following data were collected. Calculate the overall order of the reaction. Also find out the reaction rate constant.

For a reaction, 2N_(2)O_(5)(g) to 4NO_(2)(g) + O_(2)(g) rate of reaction is:

For the given reaction, A+B rarr Products following data were obtained (i) Write the rate law expression. (ii) Find the rate constant.

OP TANDON-CHEMICAL KINETICS-PRACTICE PROBLEMS
  1. For the inversion of cane, sugar, C(12)H(22)O(11)+H(2)OrarrC(6)H(12)...

    Text Solution

    |

  2. What is the rat law expressio for the reaction , A+BrarrC The foll...

    Text Solution

    |

  3. The reaction , 2N(2)O(5)rarr4NO(2)+O(2) was studdied and the foll...

    Text Solution

    |

  4. For the reaction, 2NO+2H(2)rarrN(2)+2H(2)O, the following kinetic ...

    Text Solution

    |

  5. Fill in the balanks in the following table which treats reaction of a ...

    Text Solution

    |

  6. The reaction 2NO+O(2)rarr2NO(2) follows the rate law =k[NO]^(2)[O(2)]...

    Text Solution

    |

  7. From the following data of initial concentration and rates, calculate ...

    Text Solution

    |

  8. The following initial rate data were obtianed for the reaction 2NO...

    Text Solution

    |

  9. The data given below are for the reaction of NO and Cl(2) to from NOCl...

    Text Solution

    |

  10. In the hydrogen of propyl acetate in presence of dilute HCl in aqueous...

    Text Solution

    |

  11. In a first order reaction the concentration of the reactant is reduced...

    Text Solution

    |

  12. For a first order reaction, the rate constant is 0.1 s^(-1). How much ...

    Text Solution

    |

  13. A substance decomposes following first order reaction. If the half lif...

    Text Solution

    |

  14. In a first order reaction the concentration of the reactant is reduced...

    Text Solution

    |

  15. Find the two-thirds life (t(2//3)) of a first order reaction in which ...

    Text Solution

    |

  16. A first order reaction has a specific rate of 10^(-3) "sec"^(-1) . How...

    Text Solution

    |

  17. In a hydrolysis reaction, 5 g of ethyl acetate is hydroloysed in the p...

    Text Solution

    |

  18. Calculate the half life of the reaction ArarrB, when the initial conce...

    Text Solution

    |

  19. In reaction, ArarrB +C the following data were obtained. {:("t in se...

    Text Solution

    |

  20. The first order reaction has k=1.5xx10^(-6) per second at 200^(@)C . I...

    Text Solution

    |