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In the reaction 3Ararr2B, rate of reacti...

In the reaction `3Ararr2B`, rate of reaction `+(d[B])/(dt)` is equal to :

A

`(1)/(3)(d[A])/(dt)`

B

`(2)/(3)(d[A])/(dt)`

C

`+2(d[A])/(dt)`

D

`(3)/(2)(d[A])/(dt)`

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The correct Answer is:
To solve the problem regarding the rate of reaction for the given chemical equation \( 3A \rightarrow 2B \), we need to analyze the stoichiometry of the reaction and how it relates to the rates of change of the concentrations of the reactants and products. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction is given as: \[ 3A \rightarrow 2B \] 2. **Write the Rate Expressions**: The rate of reaction can be expressed in terms of the change in concentration of the reactants and products. For the reaction: - The rate of disappearance of \( A \) is given by: \[ -\frac{1}{3} \frac{d[A]}{dt} \] - The rate of formation of \( B \) is given by: \[ \frac{1}{2} \frac{d[B]}{dt} \] 3. **Relate the Rates**: According to the stoichiometry of the reaction: \[ -\frac{1}{3} \frac{d[A]}{dt} = \frac{1}{2} \frac{d[B]}{dt} \] 4. **Express the Rate of Formation of \( B \)**: Rearranging the equation to find the rate of formation of \( B \): \[ \frac{d[B]}{dt} = -\frac{3}{2} \frac{d[A]}{dt} \] 5. **Final Expression**: Since the question asks for the rate of formation of \( B \) in terms of the rate of disappearance of \( A \), we can express it as: \[ \frac{d[B]}{dt} = \frac{2}{3} \left(-\frac{d[A]}{dt}\right) \] Therefore, the rate of formation of \( B \) is: \[ \frac{d[B]}{dt} = \frac{2}{3} \text{(rate of disappearance of A)} \] ### Conclusion: The rate of reaction \( \frac{d[B]}{dt} \) is equal to \( \frac{2}{3} \) times the rate of disappearance of \( A \).
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OP TANDON-CHEMICAL KINETICS-OBJECTIVE QUESTIONS (LEVEL-A)
  1. For the reaction,A+Brarr2C+D, which one is the incorrect statement?

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  2. In a reaction 2A(2)+B(2)rarr2A(2)B, the reactant A will desapper at :

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  3. In the reaction 3Ararr2B, rate of reaction +(d[B])/(dt) is equal to :

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  4. For the reaction, 2NOrarrN(2)+O(2), the expression -(1)/(2)(d[NO])/(dt...

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  5. Accroding to collision theory of reaction rates :

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  6. According to collision theory :

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  7. The Activation energy for a chemical reaction mainly depends upon

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  8. In a reaction, the threshold energy is equal to

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  9. Accroding to the colision theory of reaction rates, the rate of reacti...

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  10. The temeprature cofficient of a reaction is :

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  11. In general, with every 10^(@)C rise in temperature, the rate of reacti...

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  12. Activation energy of the reaction is :

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  13. The temperature coefficient of most of the reactions lies between

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  14. Accroding to Arrhenius equation, rate constant of a chemical reaction ...

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  15. In order to react, a molecule at the time of collision, must posses a ...

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  16. The activation energy of a reaction is zero. The rate constant of the ...

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  17. The activation energy of a reaction can be lowered by :

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  18. The activation energy for a hypothetical reaction A rarr X is 12.49 kc...

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  19. The plote between concentration versus time for a zero order reaction ...

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  20. The rate of reaction increases with rise in temerature because of :

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