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For the reaction, 2NOrarrN(2)+O(2), the ...

For the reaction, `2NOrarrN_(2)+O_(2)`, the expression `-(1)/(2)(d[NO])/(dt)` represents:

A

the rat of formation of NO

B

the average rate of the reaction

C

the instantaneous rate of the reaction

D

all of the above

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The correct Answer is:
To solve the question regarding the expression `-(1)/(2)(d[NO])/(dt)` for the reaction `2NO ⇌ N2 + O2`, we can follow these steps: ### Step 1: Understand the Reaction The reaction involves the decomposition of nitrogen monoxide (NO) into nitrogen (N2) and oxygen (O2). The stoichiometry of the reaction indicates that 2 moles of NO produce 1 mole of N2 and 1 mole of O2. ### Step 2: Define the Rate of Reaction In chemical kinetics, the rate of a reaction can be expressed in terms of the change in concentration of reactants and products over time. For a general reaction: \[ aA + bB \rightarrow cC + dD \] The rate of reaction can be expressed as: \[ \text{Rate} = -\frac{1}{a} \frac{d[A]}{dt} = -\frac{1}{b} \frac{d[B]}{dt} = \frac{1}{c} \frac{d[C]}{dt} = \frac{1}{d} \frac{d[D]}{dt} \] ### Step 3: Apply to the Given Reaction For the reaction `2NO ⇌ N2 + O2`, we can express the rate of reaction in terms of the concentration of NO: \[ \text{Rate} = -\frac{1}{2} \frac{d[NO]}{dt} \] Here, `[NO]` is the concentration of nitrogen monoxide. ### Step 4: Interpretation of the Expression The expression `-(1)/(2)(d[NO])/(dt)` specifically represents the rate at which NO is being consumed in the reaction. Since NO is a reactant, its concentration decreases as the reaction proceeds. The negative sign indicates that the concentration of NO is decreasing over time. ### Step 5: Conclusion Thus, the expression `-(1)/(2)(d[NO])/(dt)` represents the instantaneous rate of the reaction, which is the rate at a specific moment in time. ### Final Answer The expression `-(1)/(2)(d[NO])/(dt)` represents the instantaneous rate of the reaction. ---
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OP TANDON-CHEMICAL KINETICS-OBJECTIVE QUESTIONS (LEVEL-A)
  1. In a reaction 2A(2)+B(2)rarr2A(2)B, the reactant A will desapper at :

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  2. In the reaction 3Ararr2B, rate of reaction +(d[B])/(dt) is equal to :

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  3. For the reaction, 2NOrarrN(2)+O(2), the expression -(1)/(2)(d[NO])/(dt...

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  4. Accroding to collision theory of reaction rates :

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  5. According to collision theory :

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  6. The Activation energy for a chemical reaction mainly depends upon

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  7. In a reaction, the threshold energy is equal to

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  8. Accroding to the colision theory of reaction rates, the rate of reacti...

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  9. The temeprature cofficient of a reaction is :

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  10. In general, with every 10^(@)C rise in temperature, the rate of reacti...

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  11. Activation energy of the reaction is :

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  12. The temperature coefficient of most of the reactions lies between

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  13. Accroding to Arrhenius equation, rate constant of a chemical reaction ...

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  14. In order to react, a molecule at the time of collision, must posses a ...

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  15. The activation energy of a reaction is zero. The rate constant of the ...

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  16. The activation energy of a reaction can be lowered by :

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  17. The activation energy for a hypothetical reaction A rarr X is 12.49 kc...

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  18. The plote between concentration versus time for a zero order reaction ...

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  19. The rate of reaction increases with rise in temerature because of :

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  20. Which of the following is a first order reaction ?

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