Home
Class 12
CHEMISTRY
For the reaction NH(4)^(+)+OCN^(-)rarrNH...

For the reaction `NH_(4)^(+)+OCN^(-)rarrNH_(2)CONH_(2),` rthe probable mechanism is,
`NH_(4)^(+)+OCN^(-)hArrNH_(4)OCN" "` (fast)
and `NH_(4)OCNrarrCONH_(2)" "` (slow)
The rate law will be :

A

rate =`k[NH_(2)CONH_(2)]`

B

rate =`k[NH_(4)]^(+)[OCN]^(-)`

C

rate =`k[NH_(4)OCN]`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-B) SET I|48 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-B) SET II|13 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise PRACTICE PROBLEMS|70 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    OP TANDON|Exercise Integer|4 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos

Similar Questions

Explore conceptually related problems

The rate expresison for the reaction: NH_(4)CNO hArr NH_(2)CONH_(2) can be derived form the mechanism: (i) NH_(4)CNO underset(k_(2))overset(k_(1))hArr NH_(4)NCO ("Fast") (ii) NH_(4)CNO overset(k_(3))rarrNH_(3) + HNCO ("fast") (iii) NH_(3)+HNCo overset(k_(4))rarr NH_(2)CONH_(2) (Slow) Which of the following statement (s) is/are correct about the rate expresison?

For the reaction NH_(4)HS(s)rArrNH_(3)(g)+H_(2)S(g) ,K_(p)=0.09 . The total pressure at equilibrum is :-

Which is true about NH_(2)^(-), NH_(3), NH_(4)^(+) ?

(NH_(4))_(2)SO_(4)+NaOH to

Write the reaction of Mg^(2+) with Na_(2) HP O_(4) in presence of NH_(4) OH and NH_(4) CI.

For the reaction, 4NH_(3(g))+5O_(2(g))rarr 4NO_((g))+6H_(2)O_((g)) , the rate of reaction in terms of disappearance of NH_(3) is -(d[NH_(3)])/(dt) , then write the rate expression in terms of concentration of O_(2), NO and H_(2)O .

OP TANDON-CHEMICAL KINETICS-OBJECTIVE QUESTIONS (LEVEL-A)
  1. A drop of solution (volume 0.05 mL) contains 3 xx 10^(-6) "mole" H^(o+...

    Text Solution

    |

  2. For the reaction, H(2)+I(2)overset(k(1))underset(k(2))hArr2HI. The rat...

    Text Solution

    |

  3. For the reaction NH(4)^(+)+OCN^(-)rarrNH(2)CONH(2), rthe probable mech...

    Text Solution

    |

  4. For a Ist order decomposition of A as given Therefore rate const...

    Text Solution

    |

  5. For a reaction A+3BrarrP, Rate = (-d[A])/(dt) ,the expression for the ...

    Text Solution

    |

  6. Which of the following statements is correct?

    Text Solution

    |

  7. For Xrarrk=10^(10)e^(-500//T), and for WrarrZ,k=10^(12)e^(-1000//T) at...

    Text Solution

    |

  8. For a reversible reaction where the forward reaction is exotherminc, w...

    Text Solution

    |

  9. For the reaction , A+3Brarr2C+d which one of the following is not co...

    Text Solution

    |

  10. Units of rate constant of first and zero order reactions in terms of m...

    Text Solution

    |

  11. Following is the graph between log T(50) and log a (a = initial concen...

    Text Solution

    |

  12. Following is the graph between (a-x)^(-1) and time t for second order ...

    Text Solution

    |

  13. The graph between concentration (X) of the Product and time of the rea...

    Text Solution

    |

  14. Conside the chemical reaction, N(2)(g) + 3H(2)(g)rarr2NH(3)(g) The...

    Text Solution

    |

  15. Temerature dependent equation can be written as :

    Text Solution

    |

  16. If the rate of reaction ArarrB doubles on increasing the concentratio...

    Text Solution

    |

  17. For the reaction : 2N(2)O(5)rarr4NO(g)+O(2)(g) if the concentration of...

    Text Solution

    |

  18. A first order reaction is 10% complete in 20 min. the time taken for 1...

    Text Solution

    |

  19. An endothermic reaction with high activation energy for the forward re...

    Text Solution

    |

  20. For reaction aArarrxP when [A] =2.2 m M, the rate was found to be 2.4 ...

    Text Solution

    |