Home
Class 12
CHEMISTRY
The reaction between chloroform, CHCl(3)...

The reaction between chloroform, `CHCl_(3)(g)` and chlorine `Cl_(2)(g)` to from `C Cl_(4)` is believed to occur by this series of steps :
Step1 : `Cl_(2)(g)rarrCl(g)+Cl(g)`
Step2 : `CHcl_(3)(g)+Cl(g)rarrC Cl_(3)(g)+HCl(g)`
Step3 : `C Cl_(3)(g)+Cl(g)rarrC Cl_(4)(g)`
If this reaction is first order in `CHcl_(4)` and half order in `Cl_(2)` which statement about the relative rates of steps 1,2 and 3 is correct?

A

Step 1 is the slowest

B

Step 1 and 2 must both be slow

C

Step 2 must be slower than step 1

D

Step 3 must be the slowest

Text Solution

Verified by Experts

The correct Answer is:
C
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-B) SET II|13 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise ASSERTION- REASON TYPE QUESTIONS|14 Videos
  • CHEMICAL KINETICS

    OP TANDON|Exercise OBJECTIVE QUESTIONS (LEVEL-A)|192 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    OP TANDON|Exercise Integer|4 Videos
  • Chemical Thermodynamics and Thermochemistry

    OP TANDON|Exercise Self Assessment (Integer type).|3 Videos

Similar Questions

Explore conceptually related problems

For the reaction : PCl_(5) (g) rarrPCl_(3) (g) +Cl_(2)(g) :

For the reaction, 2Cl(g) rarr Cl_2(g) , the correct option is:

For the reaction, PCl_(5)(g)to PCl_(3)(g)+Cl_(2)(g)

OP TANDON-CHEMICAL KINETICS-OBJECTIVE QUESTIONS (LEVEL-B) SET I
  1. Decomposition of H(2)O(2), is a first order reaction. A 16 volume solu...

    Text Solution

    |

  2. What is the activation energy for the reverse of this reaction? N(2)...

    Text Solution

    |

  3. The reaction between chloroform, CHCl(3)(g) and chlorine Cl(2)(g) to f...

    Text Solution

    |

  4. In the reaction, 3BrO^(-)rarrBrO(3)^(-)+2Br^(-) (aqueous alkaline m...

    Text Solution

    |

  5. Which of the following graphs is correct for the following reaction? ...

    Text Solution

    |

  6. The activation energy of a certain reaction is 87 kJ "mol"^(-1). What...

    Text Solution

    |

  7. Consider the reaction : 2H(2)(g)+2NO(g)rarrN(2)(g)+2H(2)(g) The r...

    Text Solution

    |

  8. Propane reacts with iodine in acid medium accroding to the following e...

    Text Solution

    |

  9. Arrhenius equation k=Ae^(-E(a)//RT) If the activation energy of the ...

    Text Solution

    |

  10. At 25^(@)C , the values of rate constant activation energy and Arheni...

    Text Solution

    |

  11. The observed rat of acemical reaction is substantially lower than the ...

    Text Solution

    |

  12. The reaction between NO and Cl(2) takes place in the following two ste...

    Text Solution

    |

  13. which of the following reactions will not have fractional order for A(...

    Text Solution

    |

  14. In which of the following, E(a) for backward reaction is greater than ...

    Text Solution

    |

  15. For n th order reaction (t(1//2))/(t(3//4)) depends on (n ne1) :

    Text Solution

    |

  16. For a second order reaction, 2Ararr Products, a plot of log t(1//2) v...

    Text Solution

    |

  17. For a reaction taking place in three steps, the rate consatnt are k(1)...

    Text Solution

    |

  18. For an exothermic chemical process ocuuring in two process occuring in...

    Text Solution

    |

  19. A reaction takes place in three steps with individual rate constant a...

    Text Solution

    |

  20. In the reaction, P+Q rarr R+S the time taken for 75% reaction of P i...

    Text Solution

    |