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An organic compound (A) C(5)H(9) Br whic...

An organic compound (A) `C_(5)H_(9) Br` which readily decolourises bromine water and `KMnO_(4)` solution gives (B), `C_(5)H_(11)Br` on treatment with `Sn//HCI`. The reaction of (A) with `NaNH_(2)` produces (C) with evolution of ammonia (C) neither reacts with sodium nor forms any metal acetylide but reacts with Lindlar catalyst to give (D) and on reaction with `Na//liq . NH_(3)` produces (E) .Both the compounds (D) and (E) are isomeric. Give structures of (A) to (E) with proper reasoning.

Text Solution

Verified by Experts

compound (A) is an unsaturated compound consisting a double bond as it decolourises bromine water and `KMnO_(4)` solution.
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