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CH(3)CH(2)CHO +PCI(5) to (B) ,(A) " and ...


`CH_(3)CH_(2)CHO +PCI_(5) to (B) ,(A) " and " (B) " are "`

A

gem dihalide

B

(A) gem dihlide (B) vic dihalide

C

vic dihalides

D

(A) vic dihalide (B) gem dihalide

Text Solution

Verified by Experts

The correct Answer is:
D
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CH_(3)CH_(2)CH (CHO) CH_(3) IUPAC NAME

CH_(3)CHO+HOCH_(2)CH_(2)OH rarr

CH_(3) - CH_(2) -CHO & CH_(2) =CH - CH_(2) OH are

(A) overset(HCI+ZnCI_(2))larr Me_(3)C-CH_(2)OH overset(SOCI_(2))underset(PCI_(5))underset((or))rarr (B) (A) and (B) are:

(a) Write the structures of A and B in the following reactions : (i) CH_(3)COCl overset(H_2, Pd-BaSO_(4))(to)A overset(H_(2)N-OH)(to)B (ii) CH_(3)MgBr overset(1.CO_(2))underset(2.H_(3)O^+)(to)A overset(PCl_(5))(to)B (b) Distinguish between : (i) C_(6)H_(5)-COCH_(3) " and "C_(6)H_(5)-CHO (ii) CH_(3)COOH " and " HCOOH (c) Arrange the following in the increasing order of their boiling points : (i) CH_(3)CHO, CH_(3)COOH, CH_(3)CH_(2)OH

The compound which produce propane on heating with HI in presence of red P is (a) CH_(3)CH_(2)CH_(2)I " "(b) CH_(3)CH_(2)CHO (c) CH_(3)CH_(2)CH_(2)OH " "(d)CH_(3)CH_(2)COOH

Compounds showing Cannizaro' s reaction are A) CH_(3)CH_(2)CHO ( B) CHCl_(2)CHO C) (CH_(3))_(3) C- CHO D) C_(6)H_(6)CHO

How can we distinguish chemically the following pairs of compounds? (i) CH_(3)CHO and CH_(3)COCH_(3) (ii) CH_(3)CHO and C_(6)H_(5)CHO (iii) C_(6)H_(5)COCH_(3) and C_(6)CH_(5)COC_(6)H_(5) (iv) CH_(3)CHO and CH_(3)CH_(2)CHO

OP TANDON-HALOALKANES AND HALOARENES -Objective Questions
  1. In the given set of reactions : 2-"Bromopropane " overset("alc.AgCN"...

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  2. The catalyst used in the preparation of an alkyl chloride by the actio...

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  3. CH(3)CH(2)CHO +PCI(5) to (B) ,(A) " and " (B) " are "

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  4. Which can undergo haloform reaction ?

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  5. Which of the following is a primary halide ?

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  6. Among the halogens, the one which is oxidised by nitric acid is

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  8. Which of the following is formed when the product of oxidation of chlo...

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  9. Which of the following is added to chloroform to slow down its aerial ...

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  10. Ethyl chloride reats with sodium ethoxide to form a compound 'A' which...

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  11. In which of the following compounds the carbon market with asterisk is...

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  12. The major product of the following reaction is :

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  13. A compound (A) C(5)H(10) Cl(2) on hydrolysis gives C(5)H(10)O which re...

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  14. Match List I with List II and pick the correct matching from the cod...

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  15. The correct order increasing reactivity of the following alkyl halid...

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  16. An equimolar mixture of alkylbromide (A) and ammonia gives (B) which ...

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  17. Which of the following haloalkanes is most reactive?

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  18. In the chemical reaction , CH(3)CH(2)NH(2) +CHCI(4) +3KOH to (A) +(B...

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  19. (X) +KCN to CH(3)CN overset(2H(2)//Ni)(to) CH(3)CH(2)NH(2) What is (...

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  20. C(2)H(5)CI overset("Moist")underset(Ag(2)O)(to) (A) overset(AI(2)O(3))...

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