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The removal of two atoms or groups one g...

The removal of two atoms or groups one generally hydrogen `(H^(+))` and the other a leaving group `(L^(-))` resulting in the formation of unsaturated compound is known as elimination reaction.

In `E_(1)` (elimination) reactions the C-L bond is broken heterolytically (in step 1) to form a carbocation `(" as in "S_(N^(1))` reaction) in which `(L^(-))` is lost (rate determining step). The carbocation (in step 2) loses a proton from the `beta-` carbon atom by a base (nucleophile) to form an alkene. `E_(1)` reaction is favoured in compounds in which the leaving group is at secondar `(2^(@))` or tertiary`(3^(@))` Position.
In `E_(2)` (elimination) reactions two sigma bonds are broken and a `pi-`bond is formed simultaneously.`E_(2)` reactions occur in one step through a transition state.

`E_(2)` reactions are most common in haloalkanes (particulary `1^(@)`) and better the leaving group higher is the `E_(2)` reaction. In `E_(2)` reactions, both the leaving groups should be antiplaner.
`E_(1) cb` (Elimination unimolecular conjugate base) reaction involves the removal of proton by a conjugate base (step 1) to produce carbanion which loses a leaving group to form an alkene (step 2) and is a slow step
`R_(2)CH-underset(X)underset(|)C-R_(2) '+:B^(-) "(base)" to R_(2)C=CR_(2)`
`+H-B+X^(-)`
this reaction is an example of:

A

`E_(1)` reaction

B

`E_(2)`reaction

C

`E_(1)` cb reaction

D

first order reaction

Text Solution

Verified by Experts

The correct Answer is:
B
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OP TANDON-HALOALKANES AND HALOARENES -Linked comprehension type questions passage
  1. Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS)...

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  2. Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS)...

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  3. The removal of two atoms or groups one generally hydrogen (H^(+)) and ...

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  4. The removal of two atoms or groups one generally hydrogen (H^(+)) and ...

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  5. The removal of two atoms or groups one generally hydrogen (H^(+)) and ...

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  6. The removal of two atoms or groups one generally hydrogen (H^(+)) and ...

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  7. The removal of two atoms or groups one generally hydrogen (H^(+)) and ...

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  8. S(N^(1)) reaction is a first order nucleophilic substitution e.g. CH...

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  9. S(N^(1)) reaction is a first order nucleophilic substitution e.g. CH...

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  10. S(N^(1)) reaction is a first order nucleophilic substitution e.g. CH...

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  11. S(N^(1)) reaction is a first order nucleophilic substitution e.g. CH...

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  12. S(N^(1)) reaction is a first order nucleophilic substitution e.g. CH...

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  13. Free radical halogenation takes place in the presence of light or at h...

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  14. Free radical halogenation takes place in the presence of light or at h...

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  15. Free radical halogenation takes place in the presence of light or at h...

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  16. Free radical halogenation takes place in the presence of light or at h...

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  17. Free radical halogenation takes place in the presence of light or at h...

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  18. For a typical nucleophilic aromatic substitution reaction to take plac...

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  19. For a typical nucleophilic aromatic substitution reaction to take plac...

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  20. For a typical nucleophilic aromatic substitution reaction to take plac...

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