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0.44g of a monohydric alcohol when added...

0.44g of a monohydric alcohol when added to `CH_(3)MgI` in ether librates at STP, 112`cm^(3)` of methane. With PCC the same alcohol forms a carbonyl compound that answer silver mirror test. The monohydric alcohol is `:`

A

`CH_(3)-underset(OH)underset(|)(C)H-CH_(2)-CH_(3)`

B

`(CH_(3))_(3)C-CH_(2)OH`

C

`CH_(3-underset(OH)underset(|)(C )H-CH_(2)CH_(2)CH_(3)`

D

`(CH_(3))_(2)CH-CH_(2)OH`

Text Solution

Verified by Experts

The correct Answer is:
B
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OP TANDON-ALCOHOLS, PHENOLS AND ETHERS-OBJECTIVE QUESTIONS (LEVEL-A)
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  2. (X) is :

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  4. Which among the following compounds will give a secondary alcohol on r...

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  5. The reagent most suitable for converting a primary alcohol into an ald...

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  6. In the following reaction A is

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  7. When CH(2)=CH -CO OH is reduced with LiAlH(4) the compound obtained wi...

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  8. The compound on dehydrogenation gives a ketone. The original compound ...

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  9. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  10. Which of the following will produce only one product on reduction with...

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  11. The hydrolysis of 2-bromo-3-methylbutane by S(N^(1)) mechanism gives m...

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  12. The strongest acid is :

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  13. An organic compound 'X' is oxidised by using acidified K(2)Cr(2)O(7). ...

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  14. A liquid was mixed with ethanol and a drop of concentrated H(2) SO(4) ...

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  15. The reaction involved in the oil of winter Green test is salicyclic ac...

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  16. The function of ZnCl(2) in Lucas test for alcohols is :

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  17. What are X and Y in the following reaction sequence : C(2)H(5)OH ove...

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  18. +CH(3)MgBr overset("Ether")(rarr)(A)overset(H(3)O^(+))(rarr)(B) The ...

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  19. 0.44g of a monohydric alcohol when added to CH(3)MgI in ether librates...

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  20. The correct statement regarding the following compounds :

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