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Among the following the number of alcoho...

Among the following the number of alcohols showing iodoform test is.
`CH_(3)OH,CH_(3)CH_(2)OH,(CH_(3))_(2)CHOH,(CH_(3))_(3)C-OH,CH_(3)CH_(2)CH_(2)CH_(2)OH,CH_(3)CHOHCH_(2)CH_(3),CH_(3)CH_(2)CH_(2)OH,(C_(2)H_(5))_(2)CHOH,CH_(3)CHOHCH(CH_(3))_(2)`

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The correct Answer is:
To determine the number of alcohols that show a positive iodoform test from the given list, we need to identify which of these alcohols contain either a methyl ketone group or a secondary alcohol that can be oxidized to a methyl ketone. The iodoform test is positive for: 1. Methyl ketones (RCOCH3) 2. Ethanol (which can be oxidized to acetaldehyde) 3. Secondary alcohols that can be oxidized to methyl ketones. Now, let's analyze each compound one by one: 1. **CH₃OH (Methanol)**: - This is a primary alcohol and does not give a positive iodoform test. - **Result**: No 2. **CH₃CH₂OH (Ethanol)**: - Ethanol can be oxidized to acetaldehyde (a methyl ketone), hence it gives a positive iodoform test. - **Result**: Yes 3. **(CH₃)₂CHOH (Isopropyl alcohol)**: - This is a secondary alcohol. It can be oxidized to acetone (a methyl ketone), hence it gives a positive iodoform test. - **Result**: Yes 4. **(CH₃)₃C-OH (Tert-Butyl alcohol)**: - This is a tertiary alcohol and does not give a positive iodoform test. - **Result**: No 5. **CH₃CH₂CH₂CH₂OH (Butanol)**: - This is a primary alcohol and does not give a positive iodoform test. - **Result**: No 6. **CH₃CHOHCH₂CH₃ (Butan-2-ol)**: - This is a secondary alcohol. It can be oxidized to methyl ketone, hence it gives a positive iodoform test. - **Result**: Yes 7. **CH₃CH₂CH₂OH (Propan-1-ol)**: - This is a primary alcohol and does not give a positive iodoform test. - **Result**: No 8. **(C₂H₅)₂CHOH (Diethylcarbinol)**: - This is a secondary alcohol but does not have a methyl group adjacent to the hydroxyl group, hence it does not give a positive iodoform test. - **Result**: No 9. **CH₃CHOHCH(CH₃)₂ (2-Pentanol)**: - This is a secondary alcohol. It can be oxidized to a methyl ketone, hence it gives a positive iodoform test. - **Result**: Yes Now, let's summarize the results: - Alcohols that give a positive iodoform test: - Ethanol - Isopropyl alcohol - Butan-2-ol - 2-Pentanol Thus, the total number of alcohols that show a positive iodoform test is **4**. ### Final Answer: The number of alcohols showing iodoform test is **4**.
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