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Aldehydes undergo disproportionation rea...

Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneous oxidation and reduction of a compound is scientifically called as disproportionatio.
Aldehydes having no `alpha`- hydrogen show this reaction called Cannizzaro's reactio. Few exceptions are also there to this generalisation.
The reaction may be represented as :
`C_(6)H_(5)CHO+C_(6)H_(5)CHOoverset(NaOH)underset(Delta)rarrC_(6)H_(5)COONa+C_(6)H_(5)CH_(2)OH`
Intramolecular Carrizzaro's reaction is also possible.

The aldehyde which shows Cannizzaro's reaction is :

A

HCHO

B

`C_(6)H_(5)CHO`

C

`[CH_(3)]_3-C-CHO`

D

all the these

Text Solution

Verified by Experts

The correct Answer is:
D
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