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Aldehydes undergo disproportionation rea...

Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneous oxidation and reduction of a compound is scientifically called as disproportionatio.
Aldehydes having no `alpha`- hydrogen show this reaction called Cannizzaro's reactio. Few exceptions are also there to this generalisation.
The reaction may be represented as :
`C_(6)H_(5)CHO+C_(6)H_(5)CHOoverset(NaOH)underset(Delta)rarrC_(6)H_(5)COONa+C_(6)H_(5)CH_(2)OH`
Intramolecular Carrizzaro's reaction is also possible.

Mixture of `C_(6)H_(5)CHO and HCHO` is teated with NaOH then Cannizzaro's reaction involves :

A

oxidation of HCHO

B

reduction of HCHO

C

oxidation of `C_(6)H_(5)CHO`

D

reduction of `C_(6)H_(5)CHO`

Text Solution

Verified by Experts

The correct Answer is:
A, B
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