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End product S of the reaction sequence i...

End product S of the reaction sequence is
`CH_3-CH_2Broverset(KCN)(rarr)P overset(H_2O //H^+)(rarr)Q overset(SOCl_2)(rarr) R overset((C_2H_5)_(2)Cd)(rarr)S`

A

`CH_3CH_2-CH_2-O-C_2H_5`

B

`C_2H_5COOCH_2-CH_3`

C

`CH_3-CH_2-COC_2H_5`

D

`CH_3COOC_2H_5`

Text Solution

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The correct Answer is:
To determine the end product S of the given reaction sequence, let's break down the steps involved in the transformation of the starting material through each reaction. ### Step-by-Step Solution: 1. **Starting Material**: The starting compound is `CH3-CH2Br` (Bromoethane). 2. **Reaction with KCN**: - Bromoethane reacts with potassium cyanide (KCN). - The cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon in bromoethane, leading to the substitution of bromine. - **Product after this step**: `CH3-CH2CN` (Propionitrile). 3. **Hydrolysis**: - The next step involves hydrolysis of the nitrile group (CN) in the presence of water and an acid (H⁺). - During hydrolysis, the nitrile is converted to a carboxylic acid. - **Product after this step**: `CH3-CH2COOH` (Propanoic acid). 4. **Reaction with SOCl2**: - The carboxylic acid reacts with thionyl chloride (SOCl2) to form an acyl chloride. - The hydroxyl group (OH) is replaced by a chlorine atom (Cl). - **Product after this step**: `CH3-CH2COCl` (Propionyl chloride). 5. **Reaction with (C2H5)2Cd**: - The acyl chloride reacts with diethylcadmium ((C2H5)2Cd), where cadmium acts as a nucleophile. - The nucleophile attacks the electrophilic carbonyl carbon, leading to the formation of a new carbon-carbon bond. - The leaving group (Cl) is expelled. - **Final Product S**: `CH3-CH2C(=O)C2H5` (Butyric acid derivative). ### Final Product: The end product S of the reaction sequence is `CH3-CH2C(=O)C2H5`.
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