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In the given reaction CH(3)-CHO overse...

In the given reaction
`CH_(3)-CHO overset(2HCHO //dil.Na_2CO_3)(rarr)(X)`, 'X' will be

A

`HOCH_2-CH_2-CHO`

B

`HOCH_2-overset(CH_2OH)overset(|)(C )H-CHO`

C

`HOCH_2-underset(CH_2OH)underset(|)overset(CH_2OH)overset(|)(C )-CHO`

D

`HOCH_2-underset(CH_2OH)underset(|)overset(CH_2OH)overset(|)(C )-CH_2OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of CH₃CHO with dilute sodium carbonate (Na₂CO₃), we need to understand the mechanism involved in this reaction. Here’s a step-by-step breakdown of the process: ### Step 1: Identify the Reactants The reactant in this reaction is CH₃CHO (acetaldehyde). We are also using dilute sodium carbonate (Na₂CO₃) which acts as a mild base. **Hint:** Recognize the structure of acetaldehyde and the role of sodium carbonate in the reaction. ### Step 2: Understand the Role of Sodium Carbonate Sodium carbonate (Na₂CO₃) dissociates in solution to give carbonate ions (CO₃²⁻). These carbonate ions can act as a base and abstract a proton (H⁺) from the aldehyde group of CH₃CHO. **Hint:** Consider how the base interacts with the aldehyde functional group. ### Step 3: Formation of Enolate Ion When the base abstracts a proton from the aldehyde, it forms an enolate ion. The structure of the enolate ion will have a negative charge on the carbon adjacent to the carbonyl group. **Hint:** Draw the structure of the enolate ion formed after deprotonation. ### Step 4: Nucleophilic Attack The enolate ion can now act as a nucleophile and attack another molecule of CH₂O (formaldehyde). This leads to the formation of a new carbon-carbon bond. **Hint:** Visualize how the enolate ion attacks the carbonyl carbon of formaldehyde. ### Step 5: Formation of a β-Hydroxy Aldehyde After the nucleophilic attack, the resulting structure will be a β-hydroxy aldehyde. This compound will have both a hydroxyl group (-OH) and an aldehyde group (-CHO). **Hint:** Identify the new functional groups present in the product. ### Step 6: Final Product Identification The final product after the reaction will be a compound that has two hydroxyl groups and one aldehyde group, which can be represented as CH₂(OH)CH(OH)CHO. This compound is known as a diol with an aldehyde. **Hint:** Confirm the structure and name of the final product based on the functional groups present. ### Conclusion The final product 'X' in the reaction CH₃CHO + HCHO in the presence of dilute Na₂CO₃ is a β-hydroxy aldehyde, specifically 3-hydroxybutanal. **Final Answer:** The product 'X' will be 3-hydroxybutanal (or a similar structure depending on how the reaction proceeds).
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