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Which of the following statement is corr...

Which of the following statement is correct regarding gluconic acid?

A

Gluconic acid is a dicarboxylic acid

B

Gluconic acid is obtained by oxidation of glucose with `HNO_3`

C

Gluconic acid can form cyclic (acetal/hemiacetal) structure

D

Gluconic acid is a partial oxidation product of glucose

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AI Generated Solution

The correct Answer is:
To determine the correct statement regarding gluconic acid, let's analyze each option step by step. ### Step 1: Understanding Gluconic Acid Gluconic acid is a carboxylic acid derived from glucose. It is formed when glucose undergoes oxidation. ### Step 2: Analyzing the Statements 1. **Statement A: Gluconic acid is dicarboxylic.** - **Analysis:** Gluconic acid has only one carboxylic group and one alcohol group. Therefore, this statement is incorrect. 2. **Statement B: It is obtained by oxidation of glucose by SnO3.** - **Analysis:** Gluconic acid is actually produced by the oxidation of glucose using bromine water (Br2 in water), not SnO3. Thus, this statement is also incorrect. 3. **Statement C: Gluconic acid forms cyclic acetal and hemiacetal.** - **Analysis:** Acetals and hemiacetals are typically formed from aldehydes and alcohols, and since gluconic acid is a carboxylic acid and not an aldehyde, it does not form acetal or hemiacetal. Hence, this statement is incorrect. 4. **Statement D: Gluconic acid is a partial oxidation product of glucose.** - **Analysis:** This statement is correct. Gluconic acid is indeed a partial oxidation product of glucose. If glucose were fully oxidized, it would form saccharic acid instead. ### Conclusion The correct statement regarding gluconic acid is: - **D: Gluconic acid is a partial oxidation product of glucose.**
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