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C6H5-O-CH2CH3+HI overset(Delta)(rarr)X +...

`C_6H_5-O-CH_2CH_3+HI overset(Delta)(rarr)X + Y`
Identify X and Y in the above reaction?

A

`X : C_6H_5OH, Y : CH_3CH_3`

B

`X : C_2H_5I, Y : C_6H_5CHO`

C

`X : C_6H_5I, Y : CH_3CH_2OH`

D

`X:C_6H_5OH, Y : CH_3CH_2I`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the products (X and Y) formed when the ether \( C_6H_5-O-CH_2CH_3 \) reacts with hydroiodic acid (HI) upon heating. ### Step-by-step Solution: 1. **Identify the Reactants**: The reactant is an ether, specifically \( C_6H_5-O-CH_2CH_3 \), which consists of a phenyl group \( C_6H_5 \) and an ethyl group \( CH_2CH_3 \) connected by an oxygen atom. 2. **Understand the Reaction Mechanism**: Ethers react with strong acids like HI through a mechanism that involves protonation of the ether oxygen, leading to the formation of a more reactive species. The protonation makes the ether more susceptible to cleavage. 3. **Protonation of Ether**: When HI is added to the ether, the oxygen atom of the ether gets protonated, forming a positively charged oxonium ion: \[ C_6H_5-O^+H-CH_2CH_3 \] 4. **Cleavage of the Ether**: The oxonium ion can undergo cleavage. The bond between the oxygen and the ethyl group (CH2CH3) is broken, leading to the formation of a carbocation. The bond between the oxygen and the phenyl group remains intact. 5. **Formation of Products**: - The ethyl group (CH2CH3) will leave as an ethyl cation (which is unstable) and will react with the iodide ion (I-) from HI to form ethyl iodide (CH2CH3I). - The phenyl group (C6H5) will remain attached to the oxygen, resulting in the formation of phenol (C6H5OH). 6. **Identify X and Y**: Therefore, the products of the reaction are: - **X**: Phenol \( (C_6H_5OH) \) - **Y**: Ethyl iodide \( (C_2H_5I) \) ### Final Answer: - **X = C_6H_5OH (Phenol)** - **Y = C_2H_5I (Ethyl iodide)**
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