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In the given sequence HOCH2-CHOH-CH2OH...

In the given sequence
`HOCH_2-CHOH-CH_2OH overset(Br_2//H_2O)(rarr)A + B overset(dil.NaOH)(rarr)(X)`,
X is

A

Glyceraldehyde

B

Dihydroxyacetone

C

Fructose

D

Glucose

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the given sequence of reactions and identify the final product (X). ### Step 1: Identify the starting compound The starting compound is HOCH₂-CHOH-CH₂OH, which is glycerol (a triol with three hydroxyl groups). ### Step 2: Reaction with Bromine Water When glycerol reacts with bromine water (Br₂/H₂O), it undergoes oxidation. In this reaction: - The primary alcohol groups (–CH₂OH) are oxidized to aldehydes (–CHO). - The secondary alcohol group (–CHOH–) is oxidized to a ketone (–C=O). Thus, we will have two products: - Product A: CH₂OH (oxidized to CHO, an aldehyde) - Product B: CHOH (oxidized to C=O, a ketone) ### Step 3: Identify Products A and B - Product A (from the primary alcohol): CH₂OH → CHO (an aldehyde) - Product B (from the secondary alcohol): CHOH → C=O (a ketone) ### Step 4: Reaction with Dilute NaOH Next, the products A and B undergo a reaction with dilute NaOH. In this reaction: - The dilute NaOH will abstract a proton from the aldehyde and ketone, forming a carbanion. - This carbanion will then undergo an aldol condensation reaction. ### Step 5: Aldol Condensation The aldol condensation involves the formation of a β-hydroxy aldehyde or ketone, which can further dehydrate to form an α,β-unsaturated carbonyl compound. ### Step 6: Determine Product X After performing the aldol condensation, we will end up with a compound that has multiple hydroxyl groups and a ketone functional group. The final product (X) is a sugar known as fructose. ### Final Answer Thus, the final product X is fructose. ---
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