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The ionic radii of A^(+) and B^(-) ions ...

The ionic radii of `A^(+)` and `B^(-)` ions are `0.98xx10^(-10)m` and `1.81xx10^(-10)m`.The coordination number of each ion in `AB` is :

A

4

B

8

C

2

D

6

Text Solution

Verified by Experts

The correct Answer is:
D

Given, ionic radius of cation `(A^(+))=0.98xx10^(-10)m`
Ionic radius of anion `(B^(-))=1.81xx10^(-10)m`
`therefore" Coordination number of each ion in AB = ?"`
Now, we have
`"Radius ratio"=("Radius of cation")/("Radius of anion")=(0.98xx10^(-10)m)/(1.81xx10^(-10)m)`
`=0.541`
If radius ratio range is in between `0.441-0.732`, ion would have octahedral structure with coordination number `six'.
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