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In calcium, fluoride having the florite ...

In calcium, fluoride having the florite structures. The coordination number for calcium ion `(Ca^(2+))` and fluoride ion `(F^(-))` are

A

4 and 2

B

6 and 6

C

8 and 4

D

4 and 8

Text Solution

Verified by Experts

The correct Answer is:
C

In `CaF_(2)` (Fluorite structure), `Ca^(2+)` ions are arranged in ccp arrangement (`Ca^(2+)` ions are present at all corners and at the centre of each face of the cube) while `F^(-)` ions occupy all the tetrahedral sites.

From the above figure, you can clearly see that coordination number of `f^(-)` is 4 while that of `Ca^(2+)` is 8.
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