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If NaCl is doped with 10^(-4)mol%of SrC...

If `NaCl` is doped with `10^(-4)mol%`of `SrCl_(2)` the concentration of cation vacancies will be `(N_(A)=6.02xx10^(23)mol^(-1))`

A

`6.023xx10^(15)"mol"^(-1)`

B

`6.023xx10^(16)"mol"^(-1)`

C

`6.023xx10^(17)"mol"^(-1)`

D

`6.023xx10^(14)"mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

Doping of `NaCl` with `10^(-4)"mol"%` of `SrCl_(2)` means,
100 moles of NaCl are doped with `10^(-4)` mol of `SrCl_(2)`.
`therefore` 1 mol of NaCl is doped with ltBrgt `SrCl_(2)=(10^(-4))/(100)=10^(-6)"mole"`
As each `Sr^(2+)` ion introduces one cation vacancy.
`therefore` Concentration of cation vacancies
`10^(-6)"mol/mol of "NaCl`
`=10^(-6)xx6.023xx10^(23)"mol"^(-1)`
`=6.023xx10^(17)"mol"^(-1)`
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