Home
Class 12
CHEMISTRY
the only electron in the hydrogen atom r...

the only electron in the hydrogen atom resides under ordinary conditions in the first orbit. When energy is supplied the electron moves to higher energy orbit depending on the amount of energy absorbed. It emits energy. Lyman series is formed when the electron returns to the lowest orbit while Balmer series is formed when the electron returns to second. Similarly, Paschen, Breakett and Pfund series are formed when electron returns to the third, fourth and fifth orbits from higher energy orbits respectively (as shown in figure).

Maximum number of different lines produced when electron jump from nth level to ground level is equal to
`(n(n-1))/(2).`
For example in the case of `n=4,` number of lines produced is `6.(4to3,4to2,4to1,3to2,3to1,2to1).`When an electron returns from `n_(2) "to"n_(1)` state, the number of different
lines in the spectrum will be equal to `((n_(2)-n_(1))(n_(2)-n_(1)+1))/(2)`
If the electron comes back from energy level having energy `E_(2)` to energy level having energy `E_(1),` then the difference may be expressed in terms of energy of photon as:
`E_(2)-E_(1)=DeltaE,lambda=(hc)/(DeltaE),DeltaE=hv(v-"frequency")`
Since h and c are constants `DeltaE` corresponds to definite energy: thus each transition from one energy level to another will produce a light of definite wavelength. This is actually observed as a line in the spectrum of hydrogen atom.
Wave number of line is given by the formula:
`barv=RZ^(2)((1)/(n_(1)^(2))-(1)/(n_(2)^(2)))`
where R is a Rydberg constant `(R=1.1xx10^(7)m^(-1)).`
(i) First line of a series : It is called line of longest wavelength of line of smallest energy'.
(ii) Series limit or last line of a series : It is the line of shortest wavelength or line of highest energy.
Last line of breakett series for H-atom has wavelength `lambda_(1)"Å"` and 2nd line of Lyman series has wavelength `lambda_(2)"Å"`then:

A

T F F

B

F T T

C

T F T

D

T T T

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • NUCLEAR CHEMISTRY

    RESONANCE|Exercise Exercise-3|15 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE|Exercise PART-II|26 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE|Exercise PART -III :|8 Videos
  • NITROGEN CONTAINING COMPOUNDS

    RESONANCE|Exercise ORGANIC CHEMISTRY(Nitrogen containing Compounds)|30 Videos
  • P BLOCK ELEMENTS

    RESONANCE|Exercise PART -II|24 Videos