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The radial distribution functions [P(r)]...

The radial distribution functions `[P(r)]` is used to determine the most probable radius, which is used to find the electron in a given orbital `(dP(r))/(dr)` for `1s`-orbital of hydrogen like atom having atomic number `Z`, is `(dP)/(dr)=(4Z^(3))/(a_(0)^(3))(2r-(2Zr^(2))/(a_(0)))e^(-2Zr//a_(0))` :

A

At the point maximum value of radial distribution function `(dP(r))/(dr)=0`, one antinode is present

B

Most probable radius of `Li^(2+)` is `a_(0)/3` pm

C

Most probable radius of `He^(+)` is `a_(0)/2` pm

D

Most probable radius of hydrogen atom is `a_(0)` pm

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

At the point of maximum value of RDF
`(dP)/(dr)=0`
`(2r-(2Zr^(2))/a_(0))=0, r=a_(0)/Z`
where `Z=3` for `Li^(2+)` and `Z=2` for the `He^(+), Z=1` for hydrogen.
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