Home
Class 12
CHEMISTRY
In 1908 Rutherford together with H- Geig...

In 1908 Rutherford together with H- Geiger measured the rate of emission of `alpha` particles (x) by radius (in the nature this element is represented by a single nuclide `._(88)^(226)Ra`) and found that `1.00 g` of radius emits `x=3.42xx10^(10) alpha`- particle per second.
In 1911 Ritherford and American physical chemist B. Boltwood measured the rate of formation of helium from radius. This experiment permits to obtain the most accurate value of Avogadro's number avaliable at the time, given that the value of molar volume of ideal gas was well established. To achieve this goal a sample of radium salt purified from decays products and contaning `m=192` mg of Re was put into a device an the volume of the evolved helium was measured. After 83 days `(t=83.0 "days")` of the experiment `6.58 mm^(3)` of He was collected `(V_(He)=6.58 mm^(3) "corrected to" 0^(@)C "and" 1 atm)`.
To inderstand the results of this experiment we shall need the kinetic scheme of redioactive decay of Re which is given below (half-lives are the arrows, the type of decay is below the arrows).
`Ra underset(alpha)overset( gt 1500 "years")(rarr)Rn underset(alpha)overset(3.83 "days")(rarr)RaAunderset(alpha)overset(3.05 "min")(rarr)RaBunderset(beta)overset(26.8)(rarr)RaCunderset(beta)overset(17.7 "min")(rarr)`
`rarrRaC'underset(alpha)overset(1.63xx10^(-4) S)(rarr)RaDunderset(beta)overset(27.1 "years")(rarr)RaEunderset(beta)overset(5 "days")(rarr)Pounderset(alpha)overset(138 "days")(rarr)Pb` (stable)
(RaA-RaE are intermediate products of radon decay).
Write the first six radioactive dacays using a modern natation showing atomic and mass numbers of all nuclei involved.
As a rough first approximation half-lives of all radius decay products, except those of RaD and Po, may be assumed to be negligible compared to the time of measurement t. Using this approximation perform the following calculations.

Text Solution

Verified by Experts

The correct Answer is:
`._(88)^(226)Ra rarr ._(86)^(222)Rn rarr ._(2)^(4)He`
`._(33)^(222)Rn rarr ._(84)^(218)Po rarr ._(2)^(4)He`
`._(88)^(218)Po rarr ._(82)^(214)Pb rarr ._(2)^(4)He`
`._(82)^(214)Pb rarr ._(83)^(214)Bi rarr e`
`._(83)^(214)Bi rarr ._(84)^(214)Po rarr e`
`._(84)^(214)Po rarr._(82)^(210)Pb rarr ._(2)^(4)He`
Promotional Banner

Similar Questions

Explore conceptually related problems

Calculate t_(3//2) for Am^(241) in years given that it emits 1.2 xx 10^(11) alpha -particles per gram per second

Energy of the beam of alpha -particles used by Geiger and Marsden in scattering experiment is

Emission of a beta - particle by a nuclide results in the formation _________ of the element.

In Geiger-Mersden experiment, collimation of alpha -particles into a narrow beam is done by passing

Find the half life of U^(238) , if one gram of it emits 1.24xx10^4 alpha -particle per second. Avogadro's Number =6.023xx10^(23) .

From the alpha - particle scattering experiment Rutherford concluded that