Home
Class 12
CHEMISTRY
Determine range of E^(@) values for this...

Determine range of `E^(@)` values for this reaction `X_(aq)^(2+)+2e^(-)toX(s)` for given conditions:
(a). If the metal X dissolve in `HNO_(3)` but not in `HCl` it can displace `Ag^(+)` ion but not `Cu^(2+)` ion.
(b). If te metal X is HCl acid producing `H_(2)(g)` but does not displace either `Zn^(2+)` or `Fe^(2+)`
Given `E_(Ag^(+)//Ag)^(0)=0.8V" "E_(Fe^(2+)//Fe)^(0)=-0.44`
`E_(Cu^(2+)//Cu)^(0)=0.34V" "E_(NO_(3)^(-)//NO)^(0)=0.96V" "E_(zn^(2+)//Zn)^(0)=-0.76V`

Text Solution

Verified by Experts

The correct Answer is:
(a). `0.34ltE^(@)lt0.8`
(b). `-0.44ltE^(@)lt0`

(a). Metal should below hydrogen and `Cu^(2_)` but should above `Ag^(+)` in series.
(b). Metal should above hydrogen but should below from `Zn^(2+)` and `Fe^(2+)` both.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISRY

    RESONANCE|Exercise Assertion Reasoning|11 Videos
  • ELECTROCHEMISRY

    RESONANCE|Exercise Subjective Questions|14 Videos
  • ELECTROCHEMISRY

    RESONANCE|Exercise Board Level Exercise|20 Videos
  • ELECTRO CHEMISTRY

    RESONANCE|Exercise PHYSICAL CHEMITRY (ELECTROCHEMISTRY)|53 Videos
  • EQUIVALENT CONCEPT & TITRATIONS

    RESONANCE|Exercise Part -IV|22 Videos

Similar Questions

Explore conceptually related problems

Given E_(Ag^(o+)|Ag)^(@) = + 0.80V , E_(Co^(2+)|Co)^(@) = -0.28 V, E_(Cu^(2+)|Cu)^(@) = + 0.34V, E_(Zn^(2+)|Zn)^@ = -0.76 V Which metal will corrode fastest?

Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+)(aq) +Cu(s) . Given that E_(Cu^(2+)//Cu)^(@) = 0.34 V , E_(Fe^(+2)//Fe)^(@) =- 0.44 V

Find the E_(cell)^(@) for the following cel reaction Fe^(+2)+Zn rarr Zn^(+2)+Fe Given E_(Zn//Zn^(+2))^(@)=0.76V,E_(Fe//Fe^(+2))^(@)=+0.41 V

Calculate the DeltaG^(@) of the following reaction :- Fe^(+2)(aq)+Ag^(+)(aq)toFe^(+2)(aq)+Ag(s) E_(Ag^(+)//Ag)=0.8V" "E_(Fe^(+3)//Fe^(+2))^(0)=0.77V

Find E_(cell)^(@) for the cell : Zn | Zn^(2+)(1M) || Ag^(+)(1M) | Ag [Given that : E_(Zn//Zn^(2+))^(@)=0.76" V" , E_(Ag^(+)//Ag)^(@)=0.80" V" .

Given E_(Ag^(+)//Ag)^(@)=+0.80 V, E_(Cu^(2+)//Cu)^(@)=+0.34 V, E_(Fe^(3+)//Fe^(2+))^(@)=+0.76 V, E_(Ce^(4+)//Ce^(3+))^(@)=+1.60 V Which of the following statements is not correct ?

RESONANCE-ELECTROCHEMISRY-Exercise
  1. The standard reduction potential value of the three metallic cations X...

    Text Solution

    |

  2. (i). Which of the following oxides is reduced by hydrogen? MgO,CuO a...

    Text Solution

    |

  3. Determine range of E^(@) values for this reaction X(aq)^(2+)+2e^(-)toX...

    Text Solution

    |

  4. If E(fe^(2+)//Fe)^(@) is x(1),E(Fe^(3+)//Fe)^(@), is x(2) then what wi...

    Text Solution

    |

  5. The standard reduction potential of TiO^(2+) and Ti^(3+) are given by ...

    Text Solution

    |

  6. consider the standard reduction potentials (in volts) as shown in figu...

    Text Solution

    |

  7. The standard oxidation potentials for Mn^(3+) ion acid solution are Mn...

    Text Solution

    |

  8. Using the triangleG^(0) for the reaction C+O(2)toCO(2)triangleG^(0)=...

    Text Solution

    |

  9. Make complete cell diagrams of the following cell reactions (a). Cd^...

    Text Solution

    |

  10. Write cell reaction of the following cells: (a). Pt|Fe^(2+),Fe^(3+)|...

    Text Solution

    |

  11. Calculat ethe oxidation potential of a hydrogen electrode at pH=1(T=29...

    Text Solution

    |

  12. The standard oxidation potential for the half-cell NO(2)^(-)(g)+H(2)...

    Text Solution

    |

  13. Calculate the electrode potential at 25^(@)C of Cr^(3+),Cr(2)O(7)^(2-)...

    Text Solution

    |

  14. The standard reduction potential for Cu^(2+)//Cu is +0.34V. Calculate ...

    Text Solution

    |

  15. The EMF of the cell M|M^(n+) (0.02 M) | H^(+) (1 M) | H(2)(g) (1 atm),...

    Text Solution

    |

  16. Consider the following electrochemical cell. (a). Write a balanced n...

    Text Solution

    |

  17. An electrochemical cell is constructed with an open switch as shown be...

    Text Solution

    |

  18. Equinormal solutions of two weak acids HA(pK(a)=3) and HB(pK(a)=5) are...

    Text Solution

    |

  19. In two vessels each containing 500 ml water, 0.5m mol of aniline (K(b)...

    Text Solution

    |

  20. NO(3)^(-)toNO(2) (acid medium) E^(0)=0.790V NO(3)^(-)toNH(3)OH^(+) (...

    Text Solution

    |