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The electrode potential of electrode M...

The electrode potential of electrode
`M(s) rightarrow M^(n+) (aq) (2M) + ne^(-)` at 298 K is E_(1). When temperature is doubled and concentration is made half, then the electrode potential becomes `E_(2)`. Which of the following represents the correct relationship between `E_(1)` and `E_(2)`?

A

`E_(1)gtE_(2)`

B

`E_(1)ltE_(2)`

C

`E_(1)=E_(2)`

D

Can't be predicted.

Text Solution

Verified by Experts

The correct Answer is:
B

`E_(1)=E^(@)=-(RT)/(nF)ln2`
`E_(2)=E^(@)-(Rxx2T)/(nF)ln1=E^(@)`
`thereforeE_(2)gtE_(1)`
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