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In which of the following cell(s): E("ce...

In which of the following cell(s): `E_("cell")=E_("cell")^(@)`?

A

`Cu(s)|Cu^(2+)(0.01M)||Ag^(+)(0.1M)|Ag(s)`

B

`Pt(H_(2))pH=1||Zn^(2+)(0.01M)|Zn(s)`

C

`Pt(H_(2))|pH=1||Zn^(2+)(1M)|Zn(s)`

D

`Pt(H_(2))|H^(+)=0.1M||Zn^(2+)(0.01M)|Zn(s)`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

(A). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([Ag^(+)]^(2))/([Cu^(2+)]))`
(B). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([H^(+)]^(2))/([Zn^(2+)]))`
(D). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([H^(+)]^(2))/([Zn^(2+)]))`
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